| 75234-55-8

• CAS: 75234-55-8；76317-76-5
• 化学式: C₁₇H₂₁Cl₃N₂PdS
• 分子量: 498.212
• InChiKey: PYXJHWMKAPHDKI-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  盐酸异丙嗪 、 palladium dichloride 以 盐酸 、 水 为溶剂， 以88.5%的产率得到
  参考文献：
  名称：

  Synthesis and Characterization of Palladium Dichloride Complexes of N-Alkylphenothiazines

  摘要：

  Mononuclear palladium(ll) chloride - phenothiazine complexes have been prepared. The products were characterized by their elemental analyses, molar conductivity, magnetic susceptibility, and spectroscopic data. The molecular formulas of the new complexes were found to be: [Pd(LH)Cl-3].xH(2)O where L = chlorpromazine (CP) and x = 1, L = promethazine (PM) or ethopropazine (EP) and x = 0; and [Pd(TFH2)Cl-4] .H2O where TF = trifluoperazine. All complexes, except the CP complex, are diamagnetic species. Tentative structures have been proposed.

  DOI：

  10.1080/00945719608004770

文献信息

• Co-ordination of promethazine {10-[2-(dimethyl(amino)propyl]phenothiazine} hydrochloride with palladium(II): X-ray crystal structure of a trichloro-palladium(II) product
  作者：William J. Geary、Nigel J. Mason、Leslie A. Nixon、Ian W. Nowell

  DOI：10.1039/c39800001064

  日期：——

  Potassium tetrachloropalladate reacts with promethazine hydrochloride to give a unique complex in which the protonated promethazine is sulphur-bonded to palladium and takes up a ‘scorpion’ conformation, thereby facilitating electrostatic interaction between the quaternary nitrogen on the side chain and the PdCl3 unit.

  四氯钯酸钾与异丙嗪盐酸盐反应生成独特的络合物，其中质子化的异丙嗪硫键合到钯上并占据``蝎子''构象，从而促进侧链上的季氮与PdCl 3单元之间的静电相互作用。
• Geary, William J.; Mason, Nigel J.; Nowell, Ian W., Journal of the Chemical Society, Dalton Transactions, 1982, p. 1103 - 1108
  作者：Geary, William J.、Mason, Nigel J.、Nowell, Ian W.、Nixon, Leslie A.

  DOI：——

  日期：——