[Ru(η6-p-cymene)(κ2(P,N)-(N-diisopropylphosphino-2-aminopyridine)Cl](SbF6) | 1258071-38-3

• 英文名称: [Ru(η6-p-cymene)(κ2(P,N)-(N-diisopropylphosphino-2-aminopyridine)Cl](SbF6)
• 英文别名: [Ru(η6-p-cymene)(κ2(P,N)-PN-iPr)Cl](SbF6)
• CAS: 1258071-38-3
• 化学式: C₂₁H₃₃ClN₂PRu*F₆Sb
• 分子量: 716.744
• InChiKey: QRYNNWYEDVLACS-UHFFFAOYSA-G

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Ru(η6-p-cymene)(κ2(P,N)-(N-diisopropylphosphino-2-aminopyridine)Cl](SbF6) 在 KO(t)Bu 作用下， 以 四氢呋喃 为溶剂， 以37%的产率得到[Ru(η6-p-cymene)(κ2(P,N)-PN(dep)-iPr)Cl]
  参考文献：
  名称：

  Synthesis and characterization of ruthenium p-cymene complexes bearing bidentate P–N and E–N ligands (E=S, Se) based on 2-aminopyridine

  摘要：

  The syntheses and characterization of a series of cationic of Ru(II) halfsandwich complexes of the types [Ru(eta(6)-p-cymene)(kappa(2)(P,N)-PN)Cl](+) (PN =N-diphenylphosphino-2-aminopyridine, N-di-iso-propylphosphino-2-aminopyridine, 2-[(2-pyridyl)amino]dibenzo[d,f][1,2,3]dioxaphosphepine, N-(diisopropylphosphino)-2,6-diaminopyridine) and [Ru(eta(6)-p-cymene)(kappa(2)(E,N)-EN)Cl](+) (EN = N-(2-pyridinyl)amino-diphenylphosphine sulfide, N-(2-pyridinyl)amino-diisopropylphosphine sulfide, N-(2-pyridinyl)amino-diphenylphosphine selenide, N-(2-pyridinyl)amino-diisopropylphosphine selenide) is described. Some of these complexes were tested as precatalysts for the transfer hydrogenation of acetophenone to give 1-phenyl ethanol. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2010.08.014
• 作为产物：
  描述：

  silver hexafluoroantimonate 、 [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂ 、 2-pyridineaminodiisopropylphosphine 以 二氯甲烷 为溶剂， 以85%的产率得到[Ru(η6-p-cymene)(κ2(P,N)-(N-diisopropylphosphino-2-aminopyridine)Cl](SbF6)
  参考文献：
  名称：

  Synthesis and characterization of ruthenium p-cymene complexes bearing bidentate P–N and E–N ligands (E=S, Se) based on 2-aminopyridine

  摘要：

  The syntheses and characterization of a series of cationic of Ru(II) halfsandwich complexes of the types [Ru(eta(6)-p-cymene)(kappa(2)(P,N)-PN)Cl](+) (PN =N-diphenylphosphino-2-aminopyridine, N-di-iso-propylphosphino-2-aminopyridine, 2-[(2-pyridyl)amino]dibenzo[d,f][1,2,3]dioxaphosphepine, N-(diisopropylphosphino)-2,6-diaminopyridine) and [Ru(eta(6)-p-cymene)(kappa(2)(E,N)-EN)Cl](+) (EN = N-(2-pyridinyl)amino-diphenylphosphine sulfide, N-(2-pyridinyl)amino-diisopropylphosphine sulfide, N-(2-pyridinyl)amino-diphenylphosphine selenide, N-(2-pyridinyl)amino-diisopropylphosphine selenide) is described. Some of these complexes were tested as precatalysts for the transfer hydrogenation of acetophenone to give 1-phenyl ethanol. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2010.08.014