[(1,2,3,4,5-η)-6,9,12,15,18-pentamethyl-1,6,9,12,15,18-hexahydro[60]fulleren-1-yl]iodotricarbonylmolybdenum | 1060548-21-1

• 英文名称: [(1,2,3,4,5-η)-6,9,12,15,18-pentamethyl-1,6,9,12,15,18-hexahydro[60]fulleren-1-yl]iodotricarbonylmolybdenum
• CAS: 1060548-21-1
• 化学式: C₆₈H₁₅IMoO₃
• 分子量: 1102.71
• InChiKey: ZZFSYZYJAZXYHV-DRDUWKGISA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [(1,2,3,4,5-η)-6,9,12,15,18-pentamethyl-1,6,9,12,15,18-hexahydro[60]fulleren-1-yl]bromotricarbonylmolybdenum 、 碘 以 甲苯 为溶剂， 以94%的产率得到[(1,2,3,4,5-η)-6,9,12,15,18-pentamethyl-1,6,9,12,15,18-hexahydro[60]fulleren-1-yl]iodotricarbonylmolybdenum
  参考文献：
  名称：

  Group 6 Metal Complexes of the η⁵-Pentamethyl[60]fullerene

  摘要：

  A molybdenum pentamethyl[60]fullerene bromo tricarbonyl complex, Mo(eta(5)-C60Me5)Br(CO)(3) (3), was successfully synthesized by the reaction of C60Me5Br (2) with MO(CO)(3)(EtCN)(3). Treatment of 3 with I-2 afforded an iodo complex, Mo(eta(5)-C60Me5)I(CO)(3) (4). The reaction employing C60Me5K (5) prepared from C60Me5H (1) and KH, followed by treatment with Mo(CO)(3)(EtCN)(3) and then Diazald, gave a nitrosyl complex, Mo(eta(5)-C60Me5)(NO)(CO)(2) (6). Complex 6 was converted to a molybdenum(IV) complex, Mo(eta(5)- C60Me5)Cl-2(NO)(CO) (7), by the reaction with PCl5. A molybdenum(VI) complex, Mo(eta(5)-C60Me5)O2Br (8), was obtained by exposure of 3 in air. Tungsten- and chromium-nitrosyl complexes, W(eta(5)- C60Me5)(NO)(CO)(2) (9) and Cr(eta(5)-C60Me5)(NO)(CO)(2) (10), were synthesized similarly to 6. Complex 10 gave a dithiocarbonate complex, Cr(eta(5)-C60Me5)(eta(5)-S2COEt)(NO) (11) through the reaction among 10, ethanol, and carbon disulfide. Compounds 1, 3, 4, 6, 8, and 11 were characterized by X-ray crystallography.

  DOI：

  10.1021/om800308n