[HC(C(Me)N(2,6-(i)Pr2C6H3))2]Al(SH)(μ-O)P(OEt)2 | 960589-98-4

• 英文名称: [HC(C(Me)N(2,6-(i)Pr2C6H3))2]Al(SH)(μ-O)P(OEt)2
• CAS: 960589-98-4
• 化学式: C₃₃H₅₂AlN₂O₃PS
• 分子量: 614.809
• InChiKey: NAXXRGKCBDBLJI-KSWNCPITSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [HC(C(Me)N(2,6-(i)Pr2C6H3))2]Al(SH)(μ-O)P(OEt)2 、 三甲基镓 以 甲苯 为溶剂， 以62%的产率得到[κ2-P,S-((HC((C(CH3)N(C6H3(CH(CH3)2)2))2))Al(μ-S)(μ-O)P(OEt2]GaMe2
  参考文献：
  名称：

  The Synthesis and Structure of a Heterobimetallic Alumophosphite [κ²‐P, S‐LAl(µ‐S)(µ‐O)P(OEt)₂]GaMe₂

  摘要：

  The reaction of the LAl(SH)(mu-O)P(OEt)(2) (L = HC [C(Me)NAr](-), R = 2,6-di-iPr(2)C(6)H(3)) ligand (1) with GaMe3 in toluene led to the isolation of a unique heterobimetallic aluminophosphite [kappa(2)-P, S-LAl(mu-S)(mu-O)P(OEt)(2)]GaMe2 (2). Compound 2 is a potential secondary building unit (SBU) for heterometallic materials and represents the first example of structurally characterized lipophilic phosphite of the p-block metals, in which the metal is coordinated by the phosphorus atom. Moreover, it represents the first structurally characterized example where a gallium atom is coordinated to both, sulfur and phosphorus atoms. Furthermore, it contains a rare carbon-free "true" 5-membered heterocycle Al-O-P-Ga-S.

  DOI：

  10.1080/15533170701675162
• 作为产物：
  描述：

  [HC(C(Me)N(2,6-(i)Pr2C6H3))2]Al(SH)2 、 亚磷酸二乙酯 以 四氢呋喃 为溶剂， 以96%的产率得到[HC(C(Me)N(2,6-(i)Pr2C6H3))2]Al(SH)(μ-O)P(OEt)2
  参考文献：
  名称：

  An Unknown Coordination Mode of the Phosphite Unit and a Carbon-Free Heterocycle in Two Different Heterobimetallic Alumophosphites

  摘要：

  The unique alumophosphite reagent LAI(SH)(mu-O)P(OEt)(2) was prepared and used for the synthesis of the heterobimetallic alumophosphites [{kappa(2)-S,P-LAI(S)(mu-O)P(OEt)(2)}(2)Zn] and [{kappa(4)-S,O,O-LAI(SLi)(mu-O)P(OEt)(2)}(2)]. The first contains a rare example of two carbon-free five-membered heterocycles (Al-S-Zn-P-O) connected in a spiro fashion through the zinc atom, whereas the second possesses an unknown example of a coordination environment of a phosphite unit M-O-P(mu-OEt)(2)M with an uncoordinated lone electron pair on the phosphorus center.

  DOI：

  10.1021/ic701614c