[(2-(phenylazo)aniline(1-))Ru(CO)Cl(PPh3)2] | 1192801-97-0

• 英文名称: [(2-(phenylazo)aniline(1-))Ru(CO)Cl(PPh3)2]
• CAS: 1192801-97-0
• 化学式: C₄₉H₄₀ClN₃OP₂Ru
• 分子量: 885.347
• InChiKey: UQXUGHXYARTRKO-IIVFAOJQSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  [RuHCl(CO)(PPh₃)₃] 、 2-(苯基偶氮)苯胺 以 甲苯 为溶剂， 以60%的产率得到[(2-(phenylazo)aniline(1-))Ru(CO)Cl(PPh3)2]
  参考文献：
  名称：

  Reactions of 2-(arylazo)aniline with ruthenium substrates: Isolation, characterizations and reactivities of delocalized diazoketiminato and orthometallated Ru(II) chelates

  摘要：

  Reactions of 2-(arylazo)aniline, HL-NH2 [H represents the dissociable protons upon complexation and HL-NH2 is p-RC6H4N=NC6H4-NH2; R = H for HL1-NH2; CH3 for HL2-NH2 and Cl for HL3-NH2] with Ru(H) (CO)(PPh3)(3)Cl and Ru(CO)(3)(PPh3)(2) afforded products of compositions [(HL-NH)Ru(CO)Cl(PPh3)(2)] and [(L-NH)Ru(PPh3)2(CO)], respectively. All the complexes were characterized unequivocally. The X-ray structures of the complexes 4c and 5c have been determined. The cyclic volatammograms exhibited one reversible oxidative response in the range of 0.56-0.16 V versus SCE for [(L-NH)Ru(PPh3)(2)(CO)] and a quasi reversible oxidative response within 0.56-0.70 V versus SCE for [(HL-NH)Ru(CO)Cl(PPh3)(2)]. The conversion of ketones to corresponding alcohols has been studied in presence of newly synthesized ruthenium complexes. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2009.06.038
• 作为试剂：
  描述：

  邻氯苯乙酮 在 [(2-(phenylazo)aniline(1-))Ru(CO)Cl(PPh3)2] 、 异丙醇 、 potassium hydroxide 作用下， 反应 1.5h， 以73%的产率得到1-(2-氯苯基)乙醇
  参考文献：
  名称：

  Reactions of 2-(arylazo)aniline with ruthenium substrates: Isolation, characterizations and reactivities of delocalized diazoketiminato and orthometallated Ru(II) chelates

  摘要：

  Reactions of 2-(arylazo)aniline, HL-NH2 [H represents the dissociable protons upon complexation and HL-NH2 is p-RC6H4N=NC6H4-NH2; R = H for HL1-NH2; CH3 for HL2-NH2 and Cl for HL3-NH2] with Ru(H) (CO)(PPh3)(3)Cl and Ru(CO)(3)(PPh3)(2) afforded products of compositions [(HL-NH)Ru(CO)Cl(PPh3)(2)] and [(L-NH)Ru(PPh3)2(CO)], respectively. All the complexes were characterized unequivocally. The X-ray structures of the complexes 4c and 5c have been determined. The cyclic volatammograms exhibited one reversible oxidative response in the range of 0.56-0.16 V versus SCE for [(L-NH)Ru(PPh3)(2)(CO)] and a quasi reversible oxidative response within 0.56-0.70 V versus SCE for [(HL-NH)Ru(CO)Cl(PPh3)(2)]. The conversion of ketones to corresponding alcohols has been studied in presence of newly synthesized ruthenium complexes. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2009.06.038