[Li(THF)4][Nd2Cl2(μ5-O)Li3(N(CH2CH2NSi(CH3)3)3)] | 256660-81-8

• 英文名称: [Li(THF)4][Nd2Cl2(μ5-O)Li3(N(CH2CH2NSi(CH3)3)3)]
• CAS: 256660-81-8
• 化学式: C₁₆H₃₂LiO₄*C₃₀H₇₈Cl₂Li₃N₈Nd₂OSi₆
• 分子量: 1411.09
• InChiKey: SKDFXAOSVZVRKQ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  lithium tris{2-(trimethylsilylamido)ethyl}amine 、 三氯化钕 以 四氢呋喃 为溶剂， 以58%的产率得到[Li(THF)4][Nd2Cl2(μ5-O)Li3(N(CH2CH2NSi(CH3)3)3)]
  参考文献：
  名称：

  Synthesis of a Triamidoamine Nd2Cl2(μ5-O)Li3 Cluster

  摘要：

  [Li(THF)(4)] [N'N-3](2)Nd2Cl2(mu(5)-O)Li-3] (2) ([N-3'N](3-) = ([Me3SiNCH2CH2)(3)N](3-)) was prepared by transmetallation of Li-3[N-3'N] with anhydrous neodymium trichloride in THE After recrystallization from diethyletheripentane (1:2) light blue crystals of 2 were obtained, which were characterized by single crystal X-ray diffraction. Space group: P2(1)/n, Z = 4, lattice dimensions at 203 K: a = 1260.8(3), b = 3832.5(8), c = 1569.2(3) pm, beta = 106.07(3)degrees, R-1 = 0.0541. In the anion of 2 a nearly trigonal bipyramidal [Nd2Li3(mu(5)-O)](7+) unit is observed.

  DOI：

  10.1002/(sici)1521-3749(199912)625:12<1953::aid-zaac1953>3.0.co;2-v