[(t-Bu-C5H4)Ru(CO)2SeCOC6H3-4-NO2] | 176377-42-7

• 英文名称: [(t-Bu-C5H4)Ru(CO)2SeCOC6H3-4-NO2]
• CAS: 176377-42-7
• 化学式: C₁₈H₁₇NO₅RuSe
• 分子量: 507.367
• InChiKey: WIYSHPRVTSUUQE-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  (μ-Se5)[(t-Bu-C5H4)Ru(CO)2]2 、 4-硝基苯甲酰氯 以 二氯甲烷 为溶剂， 以75%的产率得到[(t-Bu-C5H4)Ru(CO)2SeCOC6H3-4-NO2]
  参考文献：
  名称：

  Organoruthenium chalcogen complexes: synthesis of tert-butyl-cyclopentadienyl dicarbonyl ruthenium thio- and seleno-carboxylate complexes and crystal structure determination of (tBuC5H4)Ru(CO)2SCO(3-NO2C6H4) and (tBuC5A4)Ru(CO)2SeCO(3,5-(NO2)2C6H3)

  摘要：

  The substituted cyclopentadienyl organoruthenium dimers [((t)Bu-C5H4)Ru(CO)(2)](2)(I) and [(1,3-(t)Bu(2)-C5H3)Ru(CO)(2)](2)(II) were prepared from the reaction of Ru-3(CO)(12) with t-butyl cyclopentadiene or 1,3-di-t-butylcyclopentadiene. The thermal reaction of dimer I with elemental sulfur or selenium afforded mixtures of organoruthenium polysulfides and polyselenides from which the binuclear pentasulfur and pentaselenium bridged complexes [((t)Bu-C5H4)Ru(CO)(2)](2)(mu-S-5)(III) and [((t)Bu-C5H4)Ru(CO)(2)](2)(mu-Se-5)(IV) were isolated and characterized. The organoruthenium sulfides and selenides readily react with acid chlorides RCOCl to give the S-bonded and the Se-bonded monothio- and monoseleno-carboxylate derivatives ((t)Bu-C5H4)Ru(CO)(2)ECOR)(E = S, Se; R = 3-NO2-C6H4, 4-NO2-C6H4, 3,5-(NO2)(2)-C6H3). The crystal structures of [((t)Bu-C5H4)Ru(CO)(2)SCO(3-NO2-C6H4)] and [((t)Bu-C5H4)Ru(CO)(2)SeCO(3,5-(NO2)(2)C6H3)] were determined.

  DOI：

  10.1016/0022-328x(95)05872-m