di-(μ-chloro)-bis(1-(1'-naphthylazo)-2-naphtholate-O,N(β))dipalladium(II) | 884876-94-2

• 英文名称: di-(μ-chloro)-bis(1-(1'-naphthylazo)-2-naphtholate-O,N(β))dipalladium(II)
• CAS: 884876-94-2
• 化学式: C₄₀H₂₆Cl₂N₄O₂Pd₂
• 分子量: 878.418
• InChiKey: WGNSIMOVMUYKPA-RUZCOOILSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  di-(μ-chloro)-bis(1-(1'-naphthylazo)naphthyl-C(2),N(β))dipalladium(II) 、 间氯过氧苯甲酸 以 乙腈 为溶剂， 以45%的产率得到di-(μ-chloro)-bis(1-(1'-naphthylazo)-2-naphtholate-O,N(β))dipalladium(II)
  参考文献：
  名称：

  Metaloxylation of cyclopalladated 1-(1′-naphthylazo)naphthalene complexes by m-chloroperbenzoic acid: Oxygen insertion into metal–carbon(naphthyl) bond

  摘要：

  The cyclopalladation of symmetrical 1-(1'-naphthylazo)naphthalene(HL) affords dimeric complexes of the type [Pd-2(L)(2)X-2]1 (where X represents Cl or OAc). Thallium(I) cyclopentadienide cleaves the di-mu-chloro-bridge of [Pd2L2Cl2] and yields air-stable deep violet coloured monomer [PdLCp] 2 (Cp = eta(5)-cyclopentadienyl). Complexes 1 undergo regiospecific metaloxylation (M-C -> M-O-C) reaction with m-chloroperbenzoic acid (m-CPBA) at C2 and produce complexes [Pd-2(LO)(2)X-2] 3 where LOH is 1-(1'-naphthylazo)-2-hydroxynaphthalene. m-CPBA selectively metaloxylates the palladium-naphthyl sigma-bond of complex 2 giving rise to azonaphtholatocyclopenta-dienidepalladium(II) species in solution. (c) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2005.08.030