[(PhSe)7Hg4Br(pyridine)] | 935658-41-6

• 英文名称: [(PhSe)7Hg4Br(pyridine)]
• 英文别名: [(PhSe)7Hg4BrPy]
• CAS: 935658-41-6
• 化学式: C₄₇H₄₀BrHg₄NSe₇
• 分子量: 2053.83
• InChiKey: DLPDMXQVCQLDIM-UHFFFAOYSA-F

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  吡啶 、 di(phenylselenenyl)mercury 、 mercury dibromide 在 1,3-bis(4-nitrophenyl)triazene 作用下， 以 四氢呋喃 为溶剂， 以67%的产率得到[(PhSe)7Hg4Br(pyridine)]
  参考文献：
  名称：

  Dealing with 1,3-bis(4-nitrophenyl)triazene as intermediary ligand in the synthesis of polymeric (μ-Se)Hg-clusters: One-pot synthetic procedures and X-ray structural characterization of [(PhSe)7Hg4BrPy]n

  摘要：

  (PhSe)(2)Hg reacts initially with HgBr2 and further with 1,3-bis(4-nitrophenyl)triazene to give [(PhSe)(7)Hg4BrPy](n) (Py = pyridine) the first polymeric assembling of (mu-Se)Hg clusters obtained with a triazene as coordinating intermediary ligand. Each single molecule of adamantane alike [(PhSe)(7)Hg4BrPy] presents the Hg-II ions with a distorted tetrahedral configuration linked through asymmetric [mu-(Ph)Se](-) bridges. [(PhSe)(7)Hg4BrPy](n) represents an example of extended one-dimensional chains of closed anisotropic ME (E = S, Se, Te) systems. In these reactions the features of the intermediary ligands should determine the template which leads to single adamantane moieties or to fused ones. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2006.09.002