[Pt(6-methyl-2,2'-bipyridine)Cl4] | 1334551-53-9

• 英文名称: [Pt(6-methyl-2,2'-bipyridine)Cl4]
• 英文别名: [Pt(6-methyl-2,2'-dipyridine)Cl4]；[Pt(6-mbipy)Cl4]
• CAS: 1334551-53-9
• 化学式: C₁₁H₁₀Cl₄N₂Pt
• 分子量: 507.106
• InChiKey: ABYZAZKQZBSDJI-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  dihydrogen hexachloroplatinate(IV) hexahydrate 、 6-甲基-2,2′-二吡啶 以 甲醇 为溶剂， 以77.4%的产率得到[Pt(6-methyl-2,2'-bipyridine)Cl4]
  参考文献：
  名称：

  Synthesis, characterization and crystal structure determination of platinum(IV) complexes containing, bipyridine derivatives and chloride, [Pt(5,5′-dmbipy)Cl4] and [Pt(6-mbipy)Cl4]

  摘要：

  The complex [Pt(5,5'-dmbipy)Cl-4] (1) (5,5'-dmbipy is 5,5'-dimethyl-2,2'-bipyridine) was prepared from the reaction of H2PtCl6 center dot 6H(2)O with 5,5'-dimethyl-2,2'-bipyridine in methanol. The same method was employed to make [Pt(6-mbipy)Cl-4] (2) (6-mbipy is 6-methyl-2,2'-bipyridine). Both complexes were characterized by elemental analysis, IR, UV-Vis, H-1 NMR, C-13 NMR and Pt-195 NMR spectroscopy. Their solid state structures were determined by the X-ray diffraction method. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2009.06.053