[Cu2(4'-(3-pyridyl)-2,2':6',2''-terpyridine)(μ-I)I(PPh3)] | 910252-26-5

• 英文名称: [Cu2(4'-(3-pyridyl)-2,2':6',2''-terpyridine)(μ-I)I(PPh3)]
• CAS: 910252-26-5
• 化学式: C₃₈H₂₉Cu₂I₂N₄P
• 分子量: 953.55
• InChiKey: LDNSNZDDZIQMBS-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  copper(l) iodide 、 三苯基膦 、 potassium iodide 、 4'-(pyridin-3-yl)-2,2':6',2''-terpyridine 以 水 为溶剂， 以50%的产率得到[Cu2(4'-(3-pyridyl)-2,2':6',2''-terpyridine)(μ-I)I(PPh3)]
  参考文献：
  名称：

  Hydrothermal synthesis of copper complexes of 4′-pyridyl terpyridine: From discrete monomer to zigzag chain polymer

  摘要：

  Seven copper complexes [Cu(L1)I-2] (1), [Cu-2(L1)(2)I-2](2)[Cu-2(1 mu-I)(2)I-2] (2), [Cu(L2)I-2] (3), [Cu-2(L2)(mu-I)I(PPh3)] (4), [Cu-4(L2)(2)(mu-I)(2)I-2] (5), {[Cu(L2)I](2)[Cu-2(mu-I)(2)I-2]}(n), (6) and [Cu-2(L2)(mu-I)(2)](n) (7) have been prepared by reactions of ligands: 4'-(2-pyridyl)-2,2':6',2"-terpyridine (L1) and 4'-(3-pyridyl)-2,2':6',2"-terpyridine (L2) with CuI in hydrothermal conditions, respectively. By alternating the oxidations states of the metal centers, increasing stoichiometric metal/ligand ratio and introducing a second ligand, the compounds, were successfully developed from mononuclear (1 and 3) to multinuclear (2, 4 and 5) and polymers (6 and 7). The synthesis of these compounds may provide an approach for the construction of coordination compounds of 4'-pyridyl terpyridine with different nuclearity. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2006.04.035