(4-diphenylphosphine oxide)biphenyl-2-N,N-dimethylaminomethylferrocene | 1427217-94-4

• 英文名称: (4-diphenylphosphine oxide)biphenyl-2-N,N-dimethylaminomethylferrocene
• CAS: 1427217-94-4
• 化学式: C₃₇H₃₄FeNOP
• 分子量: 595.504
• InChiKey: YAURKZIULKVSHZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (4-diphenylphosphine oxide)biphenyl-2-N,N-dimethylaminomethylferrocene 在 三氯硅烷 、 三乙胺 作用下， 以 甲苯 为溶剂， 以96%的产率得到(4-diphenylphosphino)biphenyl-2-N,N-dimethylaminomethylferrocene
  参考文献：
  名称：

  1,2-Disubstituted Aryl-Based Ferrocenyl Phosphines

  摘要：

  Ferrocenylaryl- or ferrocenylheteroarylphosphines [Fe{1-PPh2(spacer)-2-NMe2CH2C5H3}(C5H5)] (spacer = 1,4-phenylene (rac-6), 1,3-phenylene (rac-7), 4,4'-biphenylene (rac-8), 2,5-thienylene (rac-9)) were prepared in a facile two-step sequence starting with Negishi cross-coupling between N,N-dimethylaminomethylferrocene and aryl halide phosphine oxides, Br-spacer-P(O)Ph-2, by reduction with trichlorosilane. All products were characterized spectroscopically (H-1, C-13, and P-31 NMR, MS, FTIR), and rac-6, the corresponding phosphine oxide rac-2, and rac-9 were also characterized by X-ray crystallography. Furthermore, the redox properties of rac-2-9 were studied by cyclic voltammetry.

  DOI：

  10.1021/om400117n
• 作为产物：
  描述：

  N,N-dimethylaminomethylferrocene 、 (4′-bromobiphenyl-4-yl)diphenylphosphine oxide 在 正丁基锂 、 zinc(II) chloride 、 bis-triphenylphosphine-palladium(II) chloride 作用下， 以 四氢呋喃 、 正己烷 为溶剂， 反应 24.0h， 以43%的产率得到(4-diphenylphosphine oxide)biphenyl-2-N,N-dimethylaminomethylferrocene
  参考文献：
  名称：

  1,2-Disubstituted Aryl-Based Ferrocenyl Phosphines

  摘要：

  Ferrocenylaryl- or ferrocenylheteroarylphosphines [Fe{1-PPh2(spacer)-2-NMe2CH2C5H3}(C5H5)] (spacer = 1,4-phenylene (rac-6), 1,3-phenylene (rac-7), 4,4'-biphenylene (rac-8), 2,5-thienylene (rac-9)) were prepared in a facile two-step sequence starting with Negishi cross-coupling between N,N-dimethylaminomethylferrocene and aryl halide phosphine oxides, Br-spacer-P(O)Ph-2, by reduction with trichlorosilane. All products were characterized spectroscopically (H-1, C-13, and P-31 NMR, MS, FTIR), and rac-6, the corresponding phosphine oxide rac-2, and rac-9 were also characterized by X-ray crystallography. Furthermore, the redox properties of rac-2-9 were studied by cyclic voltammetry.

  DOI：

  10.1021/om400117n