N,N-dimethylaminoethyl-ferrocenyl-carboxylicamide | 1054450-50-8

• 英文名称: N,N-dimethylaminoethyl-ferrocenyl-carboxylicamide
• CAS: 1054450-50-8
• 化学式: C₁₅H₂₀FeN₂O
• 分子量: 300.184
• InChiKey: ZZIQXXQIBXUVNA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  N,N-dimethylaminoethyl-ferrocenyl-carboxylicamide 在 lithium aluminium tetrahydride 作用下， 以 1,4-二氧六环 为溶剂， 生成
  参考文献：
  名称：

  Ferrocene-based amides, amines and alcohols as a platform for the design and synthesis of redox-active hybrids: Synthesis, electrochemical and computational studies

  摘要：

  DOI：

  10.1016/j.molstruc.2024.138584
• 作为产物：
  描述：

  ferrocenoyl chloride 、 N,N-二甲基乙二胺 以 二氯甲烷 、 三乙胺 为溶剂， 以76.9%的产率得到N,N-dimethylaminoethyl-ferrocenyl-carboxylicamide
  参考文献：
  名称：

  Study on Anion Electrochemical Recognition Based on a Novel Ferrocenyl Compound with Multiple Binding Sites

  摘要：

  A novel ferrocenyl anion receptor N,N,N,N-(dimethyl, ethyl, ferrocenecarboxylic amidodimethylene) ammonium fluoborate 2 with multiple binding sites was synthesized. Its anion recognition behaviors were investigated by CV, H-1 NMR and UV-vis spectrum. It was found that the combination of two interactions enforced the anion binding ability and the binding selectivity of 2 to phosphate anion. The effects of scan rate on the CV curves of 2 with phosphate were also investigated. In different scan rate, the CV curves kept stable which indicated the strong binding between 2 and phosphate. According to relationships of peak potential, peak currents and scan rate of 2 binding with phosphate, thekinetic parameters of electrode process such as diffusion coefficient D-app, surface transfer coefficient alpha n(alpha),and standard rate constant k(0) were calculated.

  DOI：

  10.1021/jp805002a

文献信息

• Non-Covalent Interactions Mimic the Covalent: An Electrode-Orthogonal Self-Assembled Layer
  作者：Deepak Badgurjar、Madison Huynh、Benjamin Masters、Anna Wuttig

  DOI：10.1021/jacs.3c04387

  日期：2023.8.16

  van der Waals interactions to prepare a self-assembled layer stable over a 2.9 V range. The layer’s voltammetric response and in situ infrared spectra mimic those reported for analogous covalently bound ferrocene. This design is electrode-orthogonal; layer self-assembly is reversible and independent of the underlying electrode material’s surface chemistry. We demonstrate that the design can be utilized

  对于能量转换和存储以及分子传感至关重要的电荷转移事件发生在带电界面上。传统上，对界面的合成控制是通过分子的电极特异性共价束缚来实现的。共价键本质上限制了分子可调电极的范围和潜在稳定性窗口。在这里，我们报告了一种与电极表面化学无关的合成策略，以分子方式定义带电界面。我们将二茂铁氧化还原报告基团附加到两亲物上，利用非共价静电和范德华相互作用来制备在 2.9 V 范围内稳定的自组装层。该层的伏安响应和原位红外光谱模拟了类似的共价键合二茂铁的报道。该设计是电极正交的；层自组装是可逆的并且与底层电极材料的表面化学无关。我们证明该设计可用于多种电极材料类别（过渡金属、碳、碳复合材料）和形态（纳米结构、平面）。我们的工作将原子级精确的两亲物有机合成与极化电极上的原位非共价自组装相结合，为带电界面的预测性和无污染合成控制奠定了基础。