2-NMe2-4-CO2Me-1,1''-biferrocene | 1267659-48-2

• 英文名称: 2-NMe2-4-CO2Me-1,1''-biferrocene
• CAS: 1267659-48-2
• 化学式: C₂₄H₂₅Fe₂NO₂
• 分子量: 471.162
• InChiKey: GULRSZBNEGCUNV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  二茂铁乙炔 、 [Fe2(μ-η1:η3-Cα(N(Me)2)Cβ(H)Cγ(H)(CO2Me))(μ-CO)(CO)(Cp)2] 以 甲苯 为溶剂， 以52%的产率得到2-NMe2-4-CO2Me-1,1''-biferrocene
  参考文献：
  名称：

  New and Selective Routes to Functionalized Biferrocenes and Terferrocenes by [3 + 2] Cycloadditions of Alkynes with Bridging C₃ Ligands in Diiron Complexes

  摘要：

  The diiron bridging enaminoalkylidene complex [Fe-2{mu-eta(1):eta(3)- C(Fc)CHCH(NMe2)}(mu-CO)(CO)-(Cp)(2)] (2), containing a ferrocenyl group on the bridging ligand, reacts with HC CR, affording the corresponding 3-R- substituted 1,1 ''-biferrocene (R = CPh2OH, 4a; R = Tol, 4b; R = CO2Me, 4c; R = CH2OH, 4d). In a related reaction, the mu-vinylaminoalkylidene complex [Fe-2{mu-eta(1):eta(3)-C-(NMe2)CHCH(CO2Me)}(mu-CO)(CO)(Cp)(2)] (1a), upon treatment with ethynylferrocene, leads to the formation of 2-NMe2-4-CO2Me- 1,1 ''-biferrocene (4f). Conversely, the mu-enaminoalkylidene complex [Fe-2{mu- eta(1):eta(3)-C(Tol)CHCH(NMe2)}(mu-CO)(CO)(Cp)(2)] (1b) reacts with ethynylferrocene, affording a mixture of monosubstituted biferrocene 4b and disubstituted 2-NMe2-4-Tol-1,1 ''-biferrocene (4e), in comparable yields. Reaction of 2 with ethynylferrocene (HC CFc) leads to the formation of a mixture of 1,3-terferrocene (5a) and the 5-NMe2-substituted 1,3-terferrocene (5b). Investigation of the reactivity of the vinyliminium complex [Fe-2{mu-eta(1):eta(3)-C(Fc)CHCNMe2}(mu-CO)-(CO)(Cp)(2)][SO3CF3] (3) with HC CCPh2OH is also reported: the reaction affords selectively the 3-NMe2-4-R-disubstituted 1, 1 ''-biferrocene (6). The molecular structure of 5a has been determined by X-ray diffraction studies.

  DOI：

  10.1021/om101162r