cis-[RhBr(CO)(ammine)] | 72382-66-2

• 英文名称: cis-[RhBr(CO)(ammine)]
• CAS: 72382-66-2
• 化学式: C₂H₃BrNO₂Rh
• 分子量: 255.861
• InChiKey: ITTVGABLLJXPLH-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  氘代甲醇 、 cis-[RhBr(CO)(ammine)] 生成
  参考文献：
  名称：

  Infrared studies on the complexes cis-[Rh(CO)2(NH3)(X)] (XCl, Br): isotopic labelling studies and normal coordinate analysis

  摘要：

  The infrared spectra (4000-50 cm(-1)) of the complexes cis-[Rh(CO)(2)(NH3)(X)] (X = Cl, Br) and their (NH3)-N-15, ND3 and (CO)-C-13 isotopomers have been determined. Empirical assignments of the infrared-active modes are based on the frequency shifts caused by selective isotopic substitution experiments. The empirical assignments have been verified by a normal coordinate analysis of the in-plane vibrational modes. The potential energy distribution reveals very little coupling between the normal vibrational modes. However, there exists some coupling between v(RhX) and v(RhC) in the chore complex. (C) 1997 Elsevier Science B.V.

  DOI：

  10.1016/s1386-1425(96)01859-8
• 作为产物：
  描述：

  [Rh(μ-Br)(CO)2]2 、 氨 以 正己烷 为溶剂， 生成 cis-[RhBr(CO)(ammine)]
  参考文献：
  名称：

  Infrared studies on the complexes cis-[Rh(CO)2(NH3)(X)] (XCl, Br): isotopic labelling studies and normal coordinate analysis

  摘要：

  The infrared spectra (4000-50 cm(-1)) of the complexes cis-[Rh(CO)(2)(NH3)(X)] (X = Cl, Br) and their (NH3)-N-15, ND3 and (CO)-C-13 isotopomers have been determined. Empirical assignments of the infrared-active modes are based on the frequency shifts caused by selective isotopic substitution experiments. The empirical assignments have been verified by a normal coordinate analysis of the in-plane vibrational modes. The potential energy distribution reveals very little coupling between the normal vibrational modes. However, there exists some coupling between v(RhX) and v(RhC) in the chore complex. (C) 1997 Elsevier Science B.V.

  DOI：

  10.1016/s1386-1425(96)01859-8