名称:
Synthesis and characterisation of [OC-6-33][OsCl2(CO)2L2] (L=phosphine). Crystal structure of [OC-6-33][OsCl2(CO)2(PEt3)2]
摘要:
A series of [OC-6-33][OsCl2(CO)(2)L-2] (L = phosphine) complexes have been prepared by cleavage of [OsCl(mu-Cl)(CO)(3)](2) with a variety of phosphines for a comparison of spectroscopic data with those for the related [OC-6-33][OsF2(CO)(2)L-2] (L = phosphine). The X-ray structural characterisation of [OC-6-33] [OsCl2(CO)(2)(PEt3)(2)] represents the first structural characterisation for this class of complex. (C) 1999 Elsevier Science Ltd. All rights reserved.
DOI:
10.1016/s0277-5387(98)00417-3