trans-[FeBr(=C=C=CPh2)(Et2PCH2CH2PEt2)2][BPh4] | 639064-29-2

• 英文名称: trans-[FeBr(=C=C=CPh2)(Et2PCH2CH2PEt2)2][BPh4]
• 英文别名: trans-[FeBr(=C=C=CPh2)(Et2PC2H4PEt2)2][BPh4]
• CAS: 639064-29-2
• 化学式: C₂₄H₂₀B*C₃₅H₅₈BrFeP₄
• 分子量: 1057.73
• InChiKey: NSCYZYAOPISOAZ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  trans-[FeBr(=C=C=CPh2)(Et2PCH2CH2PEt2)2][BPh4] 在 K[B(CH(Me)Et)3H] 作用下， 以 四氢呋喃 、 二氯甲烷 为溶剂， 以60%的产率得到trans-[FeBr(-C.tplbond.C-C(H)Ph2)(Et2PCH2CH2PEt2)2]
  参考文献：
  名称：

  Allenylidene and derived alkynyl complexes of iron(II) with the {FeBr(Et2PCH2CH2PEt2)2}+ centre

  摘要：

  The allenylidene complexes trans-[FeBr{=C=C=C(R)Ph}(dePe)(2)][BPh4] (depe=Et2PCH2CH2PEt2; R=Me 1, Ph 2) were obtained by treatment of a methanolic solution of trans-[FeBr2(depe)(2)] with the appropriate alkynol HCdropC-C(R)Ph(OH), in the presence of Na[BPh4]. The methylallenylidene ligand in 1 undergoes reversible deprotonation (by NaOMe) to yield the enynyl (or ene-yne) complex of iron(II), trans-[FeBr{-CdropC-C(=CH2)Ph}(depe)(2)] 3. The diphenylallenylidene ligand in 2 undergoes regioselective hydride gamma-addition on reaction with K[B{CH(Me)Et}(3)H] to afford the alkynyl complex trans-[FeBr{-CdropC-C(H)Ph-2}(depe)(2)] 4. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(03)00766-6
• 作为产物：
  描述：

  trans-[Fe(Br)₂(depe)_2] 、 四苯硼钠 、 1,1-二苯基-2-丙炔-1-醇 以 甲醇 为溶剂， 以81%的产率得到trans-[FeBr(=C=C=CPh2)(Et2PCH2CH2PEt2)2][BPh4]
  参考文献：
  名称：

  Allenylidene and derived alkynyl complexes of iron(II) with the {FeBr(Et2PCH2CH2PEt2)2}+ centre

  摘要：

  The allenylidene complexes trans-[FeBr{=C=C=C(R)Ph}(dePe)(2)][BPh4] (depe=Et2PCH2CH2PEt2; R=Me 1, Ph 2) were obtained by treatment of a methanolic solution of trans-[FeBr2(depe)(2)] with the appropriate alkynol HCdropC-C(R)Ph(OH), in the presence of Na[BPh4]. The methylallenylidene ligand in 1 undergoes reversible deprotonation (by NaOMe) to yield the enynyl (or ene-yne) complex of iron(II), trans-[FeBr{-CdropC-C(=CH2)Ph}(depe)(2)] 3. The diphenylallenylidene ligand in 2 undergoes regioselective hydride gamma-addition on reaction with K[B{CH(Me)Et}(3)H] to afford the alkynyl complex trans-[FeBr{-CdropC-C(H)Ph-2}(depe)(2)] 4. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(03)00766-6

文献信息

• Allenylidene Iron(II) Complexes and Their Deprotonation, Nucleophilic Addition Reactions, and Cathodic Protonation toward Alkynyl Derivatives: A Chemical and Electrochemical Study
  作者：Ana I. F. Venâncio、M. Fátima C. Guedes da Silva、Luísa M. D. R. S. Martins、João J. R. Fraústo da Silva、Armando J. L. Pombeiro

  DOI：10.1021/om050408a

  日期：2005.9.1

  (R‘ ‘ = CN (5a), MeO (5b)), respectively. Complex 2 (Y = BPh4) also leads to the cationic alkynyl compounds trans-[Fe(NCMe)−C⋮CCPh2(X)}(depe)2][BPh4] (X = NMe2 (6a), NHMe (6b)) and trans-[Fe(NCMe)−C⋮CCPh2(PMe3)}(depe)2]Y2 (Y2 = [BPh4]2 (7a), [BPh4]2-xBrx (7b)), in acetonitrile solution, upon reaction with NHMe2, NH2Me, and PMe3, respectively. The complexes have been characterized by multinuclear NMR

  亚烯基配合物反式-[FeBr（C C CRR'）（depe）2 ] [Y]（R = Me，R'= Ph，1 ; R = R'= Ph，2 ; R = R'= Et，3；； depe = Et 2 PCH 2 CH 2 PEt 2； Y = BF 4，BPh 4）是通过反式-[FeBr 2（depe）2 ]与适当的炔醇HC⋮CCRR'（OH）在MeOH和在Na [BF 4 ]或Na [BPh 4 ]的存在下。去质子化3或亲核γ-除了2导致中性烯基和炔基络合物反式-[FeBr -C⋮CC（CHMe）Et}（depe）2 ]（4）和反式-[FeBr（-C⋮CCPh 2 R''）（depe）2 ] （R′′＝ CN（5a），MeO（5b））。络合物2（Y = BPh 4）还导致阳离子炔基化合物反式-[Fe（NCMe）-C⋮CCPh 2（X）}（depe）2 ] [BPh 4 ]（X = NMe