| 1394395-17-5

• CAS: 1394395-17-5
• 化学式: C₂₂H₂₄ClN₂PPd
• 分子量: 489.293
• InChiKey: SNTDNZOBFKMZRP-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  (二苯基膦基)甲醇 以 二氯甲烷 为溶剂， 反应 24.75h， 生成
  参考文献：
  名称：

  Bifunctional N–P ligands as building blocks for construction of multilayered metallodendrimers

  摘要：

  The synthesis of 4-amino(N-methylendiphenylphosphino)pyridine (1a) and its reaction with [PdCl2(cod)], [PtCl2(cod)], [AuCl(tht)], [RuCl2(p-cymene)](2), [RhCl(cod)](2) and [Pd(eta(3)-2-MeC3H4)Cl](2) to give [PdCl2(1a)(2)] (2), [PtCl2(1a)(2)] (3), [AuCl(1a)] (4), [RuCl2(p-cymene)(1a)] (5), [RhCl(cod)(1a)] (6) and [Pd(eta(3)-2-MeC3H4)Cl(1a)] (7) respectively are described. The new chelate complex [Pd(eta(3)-2-MeC3H4) (py-N(CH2-PPh2)(2))](OTf) (8) is also reported. Compounds 5 and 8 were characterized by single crystal X-ray diffraction. In all complexes prepared the metal atoms appear to be bonded through the P atom of 1a. The metalloligands 4, 5 and 8 have been reacted with the ruthenocarbosilanedendrimer 10 to afford new Ru-Au and Ru-Pd concentric metal layered dendrimers 11, 12 and 13. (C) 2012 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2012.06.010