(η(5)-C5H4CH2C(O)OCH2CH3)Mn(CO)3 | 175875-79-3

• 英文名称: (η(5)-C5H4CH2C(O)OCH2CH3)Mn(CO)3
• CAS: 175875-79-3
• 化学式: C₁₂H₁₁MnO₅
• 分子量: 290.154
• InChiKey: RIVNXYNDUJNCFQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  五羰基溴化锰(I) 、 、 以 四氢呋喃 为溶剂， 以30.1%的产率得到(η(5)-C5H4CH2C(O)OCH2CH3)Mn(CO)3
  参考文献：
  名称：

  Synthesis and characterization of substituted cyclopentadienide ligands that may form chelates or metal dimers

  摘要：

  Nine different substituted cyclopentadienyl ligands, which have substituents that may either chelate or bridge to second metal center, have been prepared from nucleophilic substitution reactions of esters or alkyl halides with NaCp. The sodium or thallium salts of these ligands were isolated as solids and characterized by H-1 NMR. The alkyl halide and NaCp reaction proved to yield the purer salts of the ligands because of the milder reaction conditions. These salts were reacted futher with Mn(CO)(5)Br to form the corresponding manganese tricarbonyl derivatives (i.e. (C(5)H(4)R)Mn(CO)(3); where R=C(O)CH2OCH3, C(O)CH2SCH3, C(O)CH2CH2SCH3, CH2CO2CH3, CH2CO2CH2CH3, CH2CH2CO2CH3, CH2CH2CO2CH2CH3, CH2CH2O2CCH3, and CH2CH2OCH3) and Na(C5H4C(O)CH2OCH3) was reacted with Co-2(CO)(8) to form (C5H4C(O)CH2OCH3)Co(CO)(2). The manganese and cobalt compounds were characterized by elemental analysis, IR, H-1, and C-13 NMR spectra.

  DOI：

  10.1016/0022-328x(95)05802-v