[(HC((CMe)(2,6-(isopropyl)2C6H3N))2)Al(Et)(OH)] | 950685-54-8

• 英文名称: [(HC((CMe)(2,6-(isopropyl)2C6H3N))2)Al(Et)(OH)]
• 英文别名: [(HC(C(Me)N(2,6-(i-Pr)2C6H3))2)AlEt(OH)]
• CAS: 950685-54-8
• 化学式: C₃₁H₄₇AlN₂O
• 分子量: 490.709
• InChiKey: JYEGFRYRODTYRN-KSWNCPITSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  荚基化铜 、 [(HC((CMe)(2,6-(isopropyl)2C6H3N))2)Al(Et)(OH)] 以 甲苯 为溶剂， 反应 12.0h， 以41%的产率得到
  参考文献：
  名称：

  Synthesis and Characterization of Heterobimetallic Al–O–Cu Complexes toward Models for Heterogeneous Catalysts on Metal Oxide Surfaces

  摘要：

  The beta-diketiminato aluminum-monohydroxide and -dihydroxide were reacted with tetrameric (CuMes)(4) (Mes = 2,4,6-Me3C6H2) to prepare Cu(I) complexes bearing the Al-O-Cu moiety. All complexes are characterized by elemental analysis, nuclear magnetic resonance, and single-crystal X-ray diffraction. The reaction of aluminum-monohydroxide LAlR(OH) (L = HC[C(Me)N(Ar)](2); Ar = 2,6-iPr(2)C(6)H(3); R = Me, Et) with (CuMes)(4) afforded the Cu(I) alumoxane [LAl(R)OCu center dot MesCu](2) (R = Me, 1; Et, 2). Using the aluminum-dihydroxide LAl(OH)(2) as the precursor, the dimeric [LAKOH)OCu center dot MesCu], (3) was isolated, bearing one reactive OH group on each Al center. When the reaction of LAKOH)2 with (CuMes)(4) was carried out at 70 degrees C, the dimeric octanuclear Cu(I) compound [LAl(OCu center dot MesCu)(2)](2) (4) was formed, where two residual Mes groups are located at the neighboring position on each of the two (OCu center dot MesCu)(2) squares. Compound 4 can be alternatively obtained by reacting 3 with 1 equiv of (CuMes)(4) to demonstrate the stepwise assembly of the Cu(I) alumoxanes.

  DOI：

  10.1021/acs.inorgchem.5b00990
• 作为产物：
  描述：

  2-((2,6-diisopropylphenyl)amino)-4-((2,6-diisopropylphenyl)imino)-2-pentene 以 水 、 甲苯 为溶剂， 生成 [(HC((CMe)(2,6-(isopropyl)2C6H3N))2)Al(Et)(OH)]
  参考文献：
  名称：

  New route to alkylaluminum hydroxides via hydrolysis of cyclopentadienylaluminum complexes

  摘要：

  A novel, very simple and effective synthetic method for the formation of alkylaluminum complexes with terminal hydroxy group via hydrolysis of cyclopentadienylaluminum compounds has been found. Investigations of the hydrolysis of cyclopentadienylaluminum complexes (L)Al(Me)Cp (1) and (L)Al(Et)Cp (2) (L = HC[(CMe)(2,6-'Pr(2)C(6) H(3)N)](2)) have shown that the reaction leads to the formation of (L)AI(Me)OH (3) and (L)AI(Et)OH (4), respectively. The high selectivity of the hydrolysis was revealed. The crystal structures of 1, 2 and 4 were determined. (c) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2007.05.045

文献信息

• Synthesis, structural characterization, and reactivity of the ethyl substituted aluminum hydroxide and catalytic properties of its derivative
  作者：Ying Yang、Prabhuodeyara M. Gurubasavaraj、Hongqi Ye、Zhensheng Zhang、Herbert W. Roesky、Peter G. Jones

  DOI：10.1016/j.jorganchem.2007.08.032

  日期：2008.4

  The ethyl substituted aluminum hydroxide LAlEt(OH) (2; L = HC[C(Me)N(Ar)]2; Ar = 2,6-iPr2C6H3) was prepared by the hydrolysis of LAlEt(Cl) (1) in the presence of a N-heterocyclic carbene. The reaction of 2 with Cp2ZrMe2 in toluene afforded LAlEt(μ-O)ZrMeCp2 (3) by evolution of methane, while the reaction of 2 with Cp3M in THF led to the intermolecular elimination of HCp and formation of LAlEt(μ-O)M(THF)Cp2

  通过水解LAlEt（Cl）制备乙基取代的氢氧化铝LAlEt（OH）（2 ; L = HC [C（Me）N（Ar）] 2 ; Ar = 2,6- i Pr 2 C 6 H 3） （1）在N-杂环卡宾的存在下。的反应2再用CP 2 ZrMe 2在甲苯中，得到LAlEt（μ-O）ZrMeCP 2（3）通过甲烷的演变，而反应2再用CP 3，在THF中导致HCP的分子间消除和形成LAlEt （μ-O）M（THF）CP 2（M = Yb，4 ; Er，5；Dy，6；Y，7）。通过单X射线结构分析表征化合物2和3。化合物2在正交空间群P 2 1 2 1 1 2 1中结晶，而化合物3在空间群Pnma中结晶。在这两种情况下，都可以在船形结构中观察到Al和γ-C原子从NCCN平面移出，但方向相反。此外，化合物3用作乙烯聚合的催化剂。