(1,5-cyclooctadiene)(1,1,1-tris(diphenylphosphinomethyl)ethane)iridium tetrafluoroborate | 146728-57-6

• 英文名称: (1,5-cyclooctadiene)(1,1,1-tris(diphenylphosphinomethyl)ethane)iridium tetrafluoroborate
• CAS: 146728-57-6
• 化学式: BF₄*C₄₉H₅₁IrP₃
• 分子量: 1011.89
• InChiKey: MUPMUGHBKSUDPG-ZNZJSHLGSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  氟硼酸铵 、 (1,5-cyclooctadiene)(1,1,1-tris(diphenylphosphinomethyl)ethane)iridium chloride 生成 (1,5-cyclooctadiene)(1,1,1-tris(diphenylphosphinomethyl)ethane)iridium tetrafluoroborate
  参考文献：
  名称：

  Synthesis and structure of five-coordinate tris-phosphine cyclooctadiene iridium complexes

  摘要：

  The syntheses of two new tris-phosphine cyclooctadiene (COD) iridium complexes are reported. In the first, [Ir(COD)(PMe3)3]Cl.0.5H2O, the geometry about iridium is square pyramidal. In the second, [Ir(COD)(tripod)][BF4] [tripod = 1,1,1-tris(diphenylphosphinomethyl)ethane], the geometry about iridium is trigonal bipyramidal. Both complexes are fluxional with very low activation barriers for rearrangement. These complexes are compared with other five-coordinate COD complexes reported in the literature.

  DOI：

  10.1016/s0277-5387(00)83596-2