Pd2(C6H4CH2NMe2)2(μ-Br)(μ-SC6H4Me-p) | 186540-42-1

• 英文名称: Pd2(C6H4CH2NMe2)2(μ-Br)(μ-SC6H4Me-p)
• CAS: 186540-42-1
• 化学式: C₂₅H₃₁BrN₂Pd₂S
• 分子量: 684.345
• InChiKey: FLHOKUDVSJKHNM-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  di-μ-acetato-bis{(o-dimethylaminomethylphenyl-C,N)palladium(II)} 以 氯仿 、 水 、 丙酮 为溶剂， 生成 Pd2(C6H4CH2NMe2)2(μ-Br)(μ-SC6H4Me-p)
  参考文献：
  名称：

  Synthesis and structural study of [{Pd(C6H4CH2N(CH3)2)}2(μ-Br) (μ-X)] complexes (X = hydroxide, amide or thiolate)

  摘要：

  The mixed hydroxo-bromo bridged complex [{Pd(C(6)H(4)CH(2)NMe(2))}(2)(mu-Br)(mu-OH)] (1) (C(6)H(4)CH(2)NMe(2) = 2-[(dimethylamino)methyl]phenyl) has been prepared by addition of one equivalent of NBu(4)OH to [{Pd(C(6)H(4)CH(2)NMe(2))(mu-O(2)CMe)}(2)] in acetone-water solution, followed by addition of one equivalent of LiBr. Complex 1 reacts with arylamines or thiols in 1:1 mole ratio to yield the corresponding amido- or thiolato-bromo complexes [{Pd(C(6)H(4)CH(2)NMe(2))}(2)(mu-Br)(mu-NHR)] (R = C6H5 (2), p-MeOC(6)H(4) (3), p-MeOC(6)H(4) (4)) or [{Pd(C(6)H(4)CH(2)NMe(2))}(2)(mu-Br)(mu-SR)] (R = Et (5), (t)Bu (6), C6H5 (7), p-MeC(6)H(4) (8)), The H-1 NMR data indicate a cia arrangement of the C(6)H(4)CH(2)NMe(2) ligands. The crystal structure of compound 1 has been determined by X-ray diffraction. It crystallizes in the orthorhombic space group Pbca with a = 12.445(3), b = 18.029(3), c = 17.436(3) Angstrom. Final R = 0.039 and R(w) = 0.040 based on 2692 reflections.

  DOI：

  10.1016/s0022-328x(96)06520-5