trans-[PtCl(ClC=P(2,6-bis(trifluoromethyl)phenyl)(PPh3)2] | 866495-98-9

• 英文名称: trans-[PtCl(ClC=P(2,6-bis(trifluoromethyl)phenyl)(PPh3)2]
• 英文别名: cis-[PtCl(ClC=P(2,6-bis(trifluoromethyl)phenyl)(PPh3)2]；cis-[PtCl(CCl=PAr')(PPh3)2]
• CAS: 866495-98-9；866594-65-2
• 化学式: C₄₅H₃₃Cl₂F₆P₃Pt
• 分子量: 1046.65
• InChiKey: YGJDGTLCXMZNPO-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  (2,6-bis(trifloromethyl)phenyl)P=CCl2 、 四(三苯基膦)铂 以 苯 为溶剂， 以73%的产率得到trans-[PtCl(ClC=P(2,6-bis(trifluoromethyl)phenyl)(PPh3)2]
  参考文献：
  名称：

  Synthesis and characterisation of the platinum complexes [PtCl(CClPAr)(PPh3)2] and [PtCl(CClPAr′)(PPh3)2] as potential intermediates in the preparation of phosphaalkynes

  摘要：

  Oxidative addition reactions of Cl2C=PR (R = 2,4,6-tris(trifluoromethyl)phenyl (Ar) or 2,6-bis(trifluoromethyl)phenyl (Ar') with Pt(PPh3)(4) yield the cis and trans (at platinum) complexes [PtCl(C=PAr)(PPh3)(2)] and [PtCl(CIC=PAr')(PPh3)(2)]. All starting materials and intermediates have been characterised by NMR spectroscopy. The crystal and molecular structures of the transplatinum complexes have been determined by single-crystal X-ray diffraction at low temperature. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2005.04.029