[(hydridotris(pyrazolyl)borate)Ru(PPh3)(NH2)2]Li | 389570-17-6

• 英文名称: [(hydridotris(pyrazolyl)borate)Ru(PPh3)(NH2)2]Li
• CAS: 389570-17-6
• 化学式: C₂₇H₂₉BN₈PRu*Li
• 分子量: 615.377
• InChiKey: IBJYBTLKLGXEIE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [(hydridotris(pyrazolyl)borate)Ru(PPh3)(NH3)2][CF3SO3] 、 甲基锂 以 四氢呋喃 为溶剂， 以95%的产率得到[(hydridotris(pyrazolyl)borate)Ru(PPh3)(NH2)2]Li
  参考文献：
  名称：

  Synthesis and Reactivity of the Octahedral d⁶ Parent Amido Complexes TpRu(L)(L‘)(NH₂) (Tp = Hydridotris(pyrazolyl)borate; L = L‘ = PMe₃, P(OMe)₃; L = CO, L‘ = PPh₃) and [TpRu(PPh₃)(NH₂)₂][Li]

  摘要：

  A series of octahedral ruthenium (II) parent amido complexes of the type TpRu(L)(L')(NH2) (L/L' = neutral and two-electron-donor ligands) and [TpRu-(PPh3)(NH2)(2)][Li] (Tp = hydridotris(pyrazolyl)borate) have been prepared. Preliminary reactivity studies indicate that the amido moieties are highly basic: for example, TpRu(L)(L')(NH2) complexes deprtonate phenylacetylene at room temperature to form [TpRu(L)(L')(NH3)][PhC2] ion pairs, as determined by H-1 NMR spectroscopy.

  DOI：

  10.1021/om010739x