| 1210049-86-7

• CAS: 1210049-86-7
• 化学式: C₂₆H₅₄N₂O₈Ti₂
• 分子量: 618.483
• InChiKey: VQLNESYRLNTNEM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  titanium(IV) isopropylate 、 bis(2-methyl-2-hydroxypropyl)(2-hydroxyethyl)amine 以 甲苯 为溶剂， 以76%的产率得到
  参考文献：
  名称：

  Selective synthesis of monomeric or dimeric titanatranes via fine tuning in triethanolateamine ligand

  摘要：

  Monomeric titanatrane i-PrOTi(OCMe2CH2)(3)N (1) and dimeric titanatranes [i-PrOTi(OCH2CH2)(n)N(CH2CMe2O)(3-n)](2) (n = 1, 2; n = 2, 3) were synthesized by the reaction of Ti(O-i-Pr)(4) with a series of triethanolateamines such as (OCH2CH2)(n)N(CH2CMe2O)(3-n)(3-) (n = 0, Lig(1); n = 1, Lig(2): n = 2, Lig(3)), which vary by the number of CMe2 groups adjacent to a CH functionality from 3 (Lig(1)H(3)) to 2 (Lig(2)H(3)) to 1 (Lig(3)H(3)). The resultant titanatranes 1-3 have been characterized by Solution H-1 and C-13{H-1} NMR and their solid state structures have been determined by X-ray crystallography. Whereas compound 1 is monomeric in the solid state, compounds 2 and 3 are dimeric, due to the reduction of the steric congestion in the vicinity of the Ti. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2009.06.017