tetrabutylammonium bis(μ-benzenethiolato-S:S)hexacarbonyl-μ-pivalato-O:O'-dimolybdate(Mo-Mo) | 223437-77-2

• 英文名称: tetrabutylammonium bis(μ-benzenethiolato-S:S)hexacarbonyl-μ-pivalato-O:O'-dimolybdate(Mo-Mo)
• CAS: 223437-77-2；305366-65-8
• 化学式: C₁₆H₃₆N*C₂₃H₁₉Mo₂O₈S₂
• 分子量: 921.88
• InChiKey: UDCPDQCOCKHBSS-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  、 四丁基溴化铵 、 特戊酸钠 以 丙酮 为溶剂， 生成 tetrabutylammonium bis(μ-benzenethiolato-S:S)hexacarbonyl-μ-pivalato-O:O'-dimolybdate(Mo-Mo)
  参考文献：
  名称：

  A dimolybdenum(I) carbonyl compound with thiolate and carboxylate bridges: tetrabutylammonium bis(μ-benzenethiolato-S:S)hexacarbonyl-μ-pivalate-O:O'-dimolybdenum(Mo—Mo)

  摘要：

  In the anion of the title compound, (C16H36N)[Mo-2-(C-5 H9O2)(C6H5S)(2)(CO)(6)], each Mo atom and three terminal carbonyl groups form a fac-Mo(CO)(3) fragment, and two Mo atoms and two benzenethiolate bridgingligands form a planar Mo2S2 unit, with the two phenyl rings in an anti configuration. The pivalate acts as a conventional mu,eta(2)-ligand bridge to two Mo atoms, to form an approximately planar five-membered ring. The two [MoOS2(CO)(3)] octahedra share a common S-S edge.

  DOI：

  10.1107/s0108270198012037