1,13-diselena-5,9-dithia[13]ferrocenophane | 1380421-11-3

• 英文名称: 1,13-diselena-5,9-dithia[13]ferrocenophane
• CAS: 1380421-11-3
• 化学式: C₁₉H₂₆FeS₂Se₂
• 分子量: 532.314
• InChiKey: IPFKNEGAVHFQIC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  六氟磷酸银 、 1,13-diselena-5,9-dithia[13]ferrocenophane 、 乙腈 、 platinum(II) chloride 以 二氯甲烷 、 乙腈 为溶剂， 以50.3%的产率得到[Pt(1,13-diselena-5,9-dithia[13]ferrocenophane)](PF6)2
  参考文献：
  名称：

  Synthesis, complexation and electrochemical study of 1,13-diselena-5,9-dithia[13]ferrocenophane: Crystal structures of [ML](PF6)2 (M=Pd, Pt)

  摘要：

  A mixed donor macrocyclic ferrocenophane, 1,13-diselena-5,9-dithia[13]ferrocenophane (L), was synthesized. Reaction of L with [M(NCMe)(4)](PF6)(2) (M = Pd, Pt) led to complexes [ML](PF6)(2) (M = Pd, Pt). The structures of two complexes have been determined by X-ray crystallography. Cyclic voltammetry shows that, in [ML](PF6)(2) (M = Pd, Pt), the half-wave potential of the 1,1'-ferrocenediyl group shifts to much more positive potentials due to the strong through-space interaction between the two metals (Fe center dot center dot center dot M) and sulfur atoms. (C) 2012 Elsevier BM. All rights reserved.

  DOI：

  10.1016/j.inoche.2012.03.002
• 作为产物：
  描述：

  1,3-丙二硫醇 、 fc[Se(CH2)3Br]2 在 NaOH 作用下， 以 四氢呋喃 、 乙醇 为溶剂， 以51%的产率得到1,13-diselena-5,9-dithia[13]ferrocenophane
  参考文献：
  名称：

  Synthesis, complexation and electrochemical study of 1,13-diselena-5,9-dithia[13]ferrocenophane: Crystal structures of [ML](PF6)2 (M=Pd, Pt)

  摘要：

  A mixed donor macrocyclic ferrocenophane, 1,13-diselena-5,9-dithia[13]ferrocenophane (L), was synthesized. Reaction of L with [M(NCMe)(4)](PF6)(2) (M = Pd, Pt) led to complexes [ML](PF6)(2) (M = Pd, Pt). The structures of two complexes have been determined by X-ray crystallography. Cyclic voltammetry shows that, in [ML](PF6)(2) (M = Pd, Pt), the half-wave potential of the 1,1'-ferrocenediyl group shifts to much more positive potentials due to the strong through-space interaction between the two metals (Fe center dot center dot center dot M) and sulfur atoms. (C) 2012 Elsevier BM. All rights reserved.

  DOI：

  10.1016/j.inoche.2012.03.002