| 1198468-41-5

• CAS: 1198468-41-5
• 化学式: C₃₈H₄₀Cl₂Cu₃N₄O₁₂*C₃₈H₄₂Cl₂Cu₃N₄O₁₃
• 分子量: 2030.61
• InChiKey: TUPPAAAWHQKBLF-CVJKRDFGSA-B

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  copper(II) perchlorate hexahydrate 、 1,3-bis(2-hydroxybenzylimino)pentane 以 乙酸乙酯 为溶剂， 生成
  参考文献：
  名称：

  An unprecedented CuII–Schiff base complex existing as two different trinuclear units with strong antiferromagnetic couplings

  摘要：

  A new tetradentate N2O2 donor Schiff base ligand [OHC6H4CH=NCH2CH2CH(CH2CH3)N=CHC6H4OH = H2L] was obtained by 1:2 condensation of 1,3-diaminopentane with salicylaldehyde and has been used to synthesise an unusual copper(II) complex whose asymmetric unit presents two structurally different almost linear trinuclear units [Cu-3(mu-L)(2)(ClO4)(2)] [Cu-3(mu-L)(2)(H2O)(ClO4)(2)] (1). The ligand and the complex were characterised by elemental analysis, FT-IR, H-1 NMR and UV-Vis spectroscopy in addition electrochemical and single crystal X-ray diffraction studies were performed for the complex. The magnetic properties of 1 reveal the presence of strong intra-trimer (J(1) = -202(3) cm(-1) and J(2) = -233(3) cm(-1)) as well as very weak inter-trimer (zJ' = -0.11(1) cm(-1)) antiferromagnetic interactions. (c) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2009.07.017