| 145166-35-4

• CAS: 145166-35-4
• 化学式: C₃₆H₂₈F₁₂MoN₄O₈P₄
• 分子量: 1092.46
• InChiKey: SZXCROUDGWJUMO-JHGUSHKYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (bicyclo[2.2.1]hepta-2,5-diene)tetracarbonylmolybdenum(0) 、 以 二氯甲烷 为溶剂， 以65%的产率得到[Mo(CO)4(μ-cis-(PhNP(OCH2CF3)))2]2
  参考文献：
  名称：

  Di- and tri-metallic complexes containing two bridging cyclodiphosphazane ligands: the crystal structure of [MO₂(CO)₈{µ-cis-[PhNP(OC₆H₄Me-p)]₂}₂]

  摘要：

  The reactions of the mononuclear cyclodiphosphazane complexes, cis-[Mo(CO)(4){cis-[PhNP(OR)](2)}(2)] with [Mo(CO)(4)(nbd)] (nbd = norbornadiene). [Mo(CO)(4)(NHC5H10)(2)] or [MCl(2)(cod)] (cod = cycloocta-1,5-diene) afforded the homobimetallic complexes; [Mo-2(CO)(8){mu-cis-[PhNP(OR)](2)}(2)] (R = C(5)H(4)Me-p 5 or CH2CF3 6) or the heterobimetallic complexes. [Mo-2(CO)(8){mu-cis-[PhNP(OE)](2)}(2)MCl(2)] (R = C(6)H(4)Me-p; M = Pd 7 or Pt 8). In all the above complexes, the two metal moieties are bridged by two cyclodiphosphazane ligands. The reactions of the mononuclear complexes, cis-[M(CO)(4)(A){cis-[PhNP(OC(6)H(4)Me-p)](2)}] with (M'Cl-2(cod)] afforded the trinuclear complexes, cis-[M'Cl-2[M(CO)(4)(A){cis-[PhNP(OC(6)H(4)Me-p)](2)}](2)] (M' = Pd, M = Mo, A = P(OMe)(3) 10; M' = Pt, M = Mo. A = P(OMe)(3) 11; M' = Pd. M = W. A = NHC5H10 12; M' = Pt, M = W. A = NHC5H10 13). The structure of the complex 5 has been determined by single-crystal X-ray crystallography.

  DOI：

  10.1039/dt9950001933
• 作为产物：
  描述：

  (bicyclo[2.2.1]hepta-2,5-diene)tetracarbonylmolybdenum(0) 、 trans-{PhNP(OCH2CF3)}2 以 苯 为溶剂， 以25%的产率得到
  参考文献：
  名称：

  Organometallics of diphosphazanes

  摘要：

  The reactions of cyclodiphosphazanes [PhNP(OR)]2 (R = CH2CF3 (1) and C6H4Me-p (2)) with Group 6 metal carbonyl derivatives have been investigated. The stereochemistry of the ligand appears to play a significant role in determining its coordination behaviour. The cyclodiphosphazane 1 (isolated as the trans-isomer) affords the dinuclear complexes 9-11 in which the two metal centres are bridged by the diphosphazane ligand. In contrast the cyclodiphosphazane 2 (isolated as a 3/1 mixture of cis- and trans-isomers) yields the mononuclear complexes 3-7 in which the cyclodiphosphazane is coordinated in the eta1-fashion. The structures of [W(CO4(NHC5H10){(PhNP(OC6H4Me-p))2}] (6) and [{Mo(CO)4(NHC5H10)}2{mu-[PhNP(OCH2CF3)]2}] (9a) have been determined by X-ray crystallography.

  DOI：

  10.1016/0022-328x(92)88010-g