[4,4'-bipyridinium][SnF6] | 1027996-89-9

• 英文名称: [4,4'-bipyridinium][SnF6]
• CAS: 1027996-89-9
• 化学式: C₁₀H₁₀N₂*F₆Sn
• 分子量: 390.903
• InChiKey: YYKDUYRRPYBURU-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [4,4'-bipyridinium][SnF6] 以 neat (no solvent) 为溶剂， 生成 tin(IV) oxide
  参考文献：
  名称：

  Supramolecular ensembles with intermolecular hydrogen bonds: The synthesis and structure of (H2Phda)[SnF3]2 and (H2Bipy)[SnF6]

  摘要：

  The structures of the compounds (H(2)Phda)[SnF3](2) (I) and (H(2)Bipy)[SnF6] (II) have been determined. The main structural elements of I are anionic ([SnF3](n)(n)) polymer chains and 1,4-phenylenediamine ([C6H4(NH3)(2)](2+)) cations. The coordination polyhedron of Sn2+ is a trigonal bipyramid with a stereochemically active lone pair in the equatorial plane. The [SnF3E](n)(n-) chains are crosslinked by phenylenediamine cations through N-H...F hydrogen bonds, resulting in supramolecular ensembles. The structure of II is built of separate [SnF6](2-) complexes and 4,4'-bipyridinium ((C10H10N2)(2+)) cations linked by bifurcate N-H...F hydrogen bonds. These bonds combine the [SnF6](2-) complexes into supramolecular layers alternating along the [100] direction with a period of 1/2a.

  DOI：

  10.1134/s0036023607020040
• 作为产物：
  描述：

  4,4'-联吡啶 、 stannous fluoride 、 氢氟酸 以 水 、 异丙醇 为溶剂， 生成 [4,4'-bipyridinium][SnF6]
  参考文献：
  名称：

  Supramolecular ensembles with intermolecular hydrogen bonds: The synthesis and structure of (H2Phda)[SnF3]2 and (H2Bipy)[SnF6]

  摘要：

  The structures of the compounds (H(2)Phda)[SnF3](2) (I) and (H(2)Bipy)[SnF6] (II) have been determined. The main structural elements of I are anionic ([SnF3](n)(n)) polymer chains and 1,4-phenylenediamine ([C6H4(NH3)(2)](2+)) cations. The coordination polyhedron of Sn2+ is a trigonal bipyramid with a stereochemically active lone pair in the equatorial plane. The [SnF3E](n)(n-) chains are crosslinked by phenylenediamine cations through N-H...F hydrogen bonds, resulting in supramolecular ensembles. The structure of II is built of separate [SnF6](2-) complexes and 4,4'-bipyridinium ((C10H10N2)(2+)) cations linked by bifurcate N-H...F hydrogen bonds. These bonds combine the [SnF6](2-) complexes into supramolecular layers alternating along the [100] direction with a period of 1/2a.

  DOI：

  10.1134/s0036023607020040