| 135624-49-6

• CAS: 135624-49-6
• 化学式: C₃₀H₂₈Mo₂N₂O₁₀P₂S
• 分子量: 862.453
• InChiKey: DTPKIHVGDNDNKP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  Di-tert-butylphosphino(diphenylphosphino)schwefeldiimid 、 molybdenum hexacarbonyl 以 四氢呋喃 为溶剂， 以26%的产率得到
  参考文献：
  名称：

  Die Carbonylchrom-, Carbonylmolybdän- und Carbonylwolfram-Komplexe der Unsymmetrisch Substituierten Phosphinoschwefeldiimide tBu2P(NSN)PPh2 und tBu2P(NSN)P(tBu)Ph. 1H, 13C und 31P NMR-Spektroskopische Charakterisierung

  摘要：

  In addition to the carbonylmetal complexes of bis(di-tert-butylphosphino) sulfur diimide, (t)Bu2P(NSN)P(t)Bu2 (1), carbonylmetal derivatives of the unsymmetrically substituted phosphino sulfur diimides (t)Bu2P(NSN)PPh2 (2) and (t)Bu2(NSN)P((t)Bu)Ph (3) have been prepared and characterized by NMR, IR and mass spectroscopy. In the presence of THF-stabilized pentacarbonylmetal 16-electron complex fragments, [M(CO)5] (M = Cr (a), Mo (b), W (c)), 2 and 3 react to give binuclear complexes [(CO)5M](t)Bu2P(NSN)P(R)Ph[M(CO)5] (R = Ph (4a-c), (t)Bu (5a-c)). The norbornadiene compounds M(CO)4(nor-C7H8) can be used to prepare chelate complexes of 2 and 3 with 14-electron complex fragments, [M(CO)4], i.e. (t)Bu2P(NSN)P(R)Ph[M(CO)4] (R = Ph (6a-c), (t)Bu (7a-c)). The structures of the new complexes were established on the basis of their H-1, C-13 and P-31 NMR spectra. As a result of the different substitution at the two phosphorus centers in 2 and 3, a variety of NMR parameters can be obtained which are not easily accessible for symmetrically substituted phosphino sulfur diimides such as 1 and their metal complexes.On the basis of the P-31 NMR spectra it is assumed that the binuclear complexes 4a-c and 5a-c are fluxional molecules in solution and undergo configurational Z/E reversible E/Z interconversion; no significant signal broadening or splitting could be observed down to -90-degrees-C in the cases of S(N-P(t)Bu2[Cr(CO)5])2 and [(CO)5Mo](t)Bu2P(NSN)PPh2[Mo(CO)5] (4b). Hahn-spin-echo experiments were used to determine coupling constants 1J(P-31,N-15). The C-13-NMR spectra of the chiral chelate complexes (t)Bu2P(NSN)P((t)Bu)Ph[M(CO)4] (7a-c) are temperature-dependent, indicating restricted rotation of the phenyl substituent around the P-C bond (DELTA-G double ended dagger = 57.1 +/- 1 kJ/mol in 7c).

  DOI：

  10.1016/0022-328x(91)80005-5