Ferrari, A.; Baroni, A., Atti della Accademia Nazionale dei Lincei, Classe di Scienze Fisiche, Matematiche e Naturali, Rendiconti, 1927, vol. 6, p. 418 - 422
作者:M. K. Khripun、K. Yu. Chervonenko、A. A. Kiselev、V. P. Petranovskii
DOI:10.1023/a:1020465819962
日期:——
Classical complex formation processes in the multicomponent systems Cd(NO3)(2)-MCl-H2O. (M = Li, Cs) occur at pre-eutectic concentrations of salts. At posteutectic concentrations of salts the formation of cadmium chloride complexes is of structurally enforced nature and depends on the type of the cybotactic. group dominating in the solution. The example of the system Cd(NO3)2-LiCl-H2O was used to show that the law of mass action does not apply to systems in which structurally enforced processes occur. Differences in the solubility of MCl (M = Li, Cs, Na) in concentrated solutions of cadmium nitrate are proposed to explain in, terms of differences in interactions of cybotactic groups formed by cadmium nitrate and the corresponding chloride.