CpFe(CO)2(C6H4(Bpin)-4) | 1048699-48-4

• 英文名称: CpFe(CO)2(C6H4(Bpin)-4)
• CAS: 1048699-48-4
• 化学式: C₁₉H₂₁BFeO₄
• 分子量: 380.031
• InChiKey: NKPHOZWWVGUGJO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  CpFe(CO)2(C6H4(Bpin)-4) 、 3-(三氟甲基)苯乙烯 以 xylene 为溶剂， 以16%的产率得到1-(3,3-difluoro-2-phenyl-2-propen-1-yl)-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzene
  参考文献：
  名称：

  Arylation of Styrenes with Aryliron Complexes [CpFe(CO)₂Ar]

  摘要：

  Treatment of aryliron complexes [CpFe(CO)(2)Ar] with styrenes in boiling xylene affords the corresponding stilbenes. The aryliron complexes, which become active upon heating, serve as arylating agents in the reaction.

  DOI：

  10.1021/om1001952
• 作为产物：
  描述：

  dicarbonylcyclopentadienyliodoiron(II) 以 not given 为溶剂， 生成 CpFe(CO)2(C6H4(Bpin)-4)
  参考文献：
  名称：

  Arylation of Styrenes with Aryliron Complexes [CpFe(CO)₂Ar]

  摘要：

  Treatment of aryliron complexes [CpFe(CO)(2)Ar] with styrenes in boiling xylene affords the corresponding stilbenes. The aryliron complexes, which become active upon heating, serve as arylating agents in the reaction.

  DOI：

  10.1021/om1001952

文献信息

• Synthesis of Aryliron Complexes by Palladium-Catalyzed Transmetalation between [CpFe(CO)₂I] and Aryl Grignard Reagents and Their Chemistry Directed toward Organic Synthesis
  作者：Shigeo Yasuda、Hideki Yorimitsu、Koichiro Oshima

  DOI：10.1021/om800560m

  日期：2008.8.1

  Palladium-catalyzed transmetalation between [CpFe(CO)2I] and aryl Grignard reagents emerges as a new method for the synthesis of [CpFe(CO)2Ar]. The aryliron complexes thus formed are useful arylmetal reagents that become active upon oxidation or UV irradiation.

  钯催化[CpFe（CO）2 I]与芳基格氏试剂之间的金属转移反应是一种合成[CpFe（CO）2 Ar]的新方法。如此形成的芳基铁配合物是有用的芳基金属试剂，其在氧化或紫外线照射下具有活性。