cis-trans-(bipyridine-N,N')dicarbonyl[diphenyl(2-phenyl-4,4,6,6-tetrachloro-2-cyclotriphosphazenyl)phosphine-P](triphenyl phosphite-P)manganese(I) hexafluorophosphate | 161044-70-8

• 英文名称: cis-trans-(bipyridine-N,N')dicarbonyl[diphenyl(2-phenyl-4,4,6,6-tetrachloro-2-cyclotriphosphazenyl)phosphine-P](triphenyl phosphite-P)manganese(I) hexafluorophosphate
• CAS: 161044-70-8
• 化学式: C₄₈H₃₈Cl₄MnN₅O₅P₅*F₆P
• 分子量: 1261.44
• InChiKey: LIFJERBUMWBNTO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  thallium(I) hexafluorophosphate 、 diphenyl(2-phenyl-4,4,6,6-tetrachloro-2-cyclotriphosphazenyl)phosphine-P 、 以 二氯甲烷 为溶剂， 以60%的产率得到cis-trans-(bipyridine-N,N')dicarbonyl[diphenyl(2-phenyl-4,4,6,6-tetrachloro-2-cyclotriphosphazenyl)phosphine-P](triphenyl phosphite-P)manganese(I) hexafluorophosphate
  参考文献：
  名称：

  cis-trans-[{N3P3Cl4(C6H5)(PPh2)}Mn(CO)2(bipy){P(OPh)3}]PF6. A Cationic Manganese–Carbonyl Complex with a Phosphazenylphosphine Ligand

  摘要：

  The structure of cis-trans-(bipyridine-N,N')dicarbonyl-[diphenyl(2-phenyl-4,4,6,6-tetrachloro-2-cyclotriphos-phazenyl)phosphine-P](triphenyl phosphite-P)manganese(I) hexafluorophosphate, [Mn(C18H15O3P)(C10H8N2)(C18H15Cl4N3P4)(CO)(2)]PF6, consists of discrete complex cations and PF6- anions linked by several weak C-H...O and C-H...F interactions. The cation is a very distorted octahedral manganese-dicarbonyl fragment having cis-trans stereochemistry and bearing triphenylphosphite, bipyridine and phosphazenylphosphine [N3P3Cl4(Ph)(PPh(2))] ligands. Analysis of the structure of the complex reveals that the coordination of the phosphazenylphosphine ligand to the cationic manganese-carbonyl fragment induces only minor changes in the phosphazene ring, affecting only the P5-P3 bond length.

  DOI：

  10.1107/s0108270194006943