N,N'-bis(2-pyridylmethyl)acetamidine zinc(II) chloride | 1295591-45-5

• 英文名称: N,N'-bis(2-pyridylmethyl)acetamidine zinc(II) chloride
• CAS: 1295591-45-5
• 化学式: C₁₄H₁₆Cl₂N₄Zn
• 分子量: 376.604
• InChiKey: VMFSGSXDEIHCSV-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  N,N'-bis(2-pyridylmethyl)acetamidine 、 zinc(II) chloride 以 四氢呋喃 为溶剂， 以82%的产率得到N,N'-bis(2-pyridylmethyl)acetamidine zinc(II) chloride
  参考文献：
  名称：

  Synthesis and crystal structures of dinuclear zinc complexes with the 1,3-bis(2-pyridylmethyl)acetamidinato ligand

  摘要：

  The reaction of an equimolar mixture of N,N'-bis(2-pyridylmethyl)acetamidine (1) and di(tert-butyl)phosphane with dimethylzinc yields dinuclear bis(methylzinc) bis(2-pyridylmethyl) acetamidinate di (tert-butyl)phosphanide (2). A similar protocol allows the preparation of bis(alkylzinc) bis(2-pyridylmethyl) acetamidinate tert-butylamide [zinc-bound methyl (3) or trimethylsilylmethyl group (4)]. The reactions of 3 and 4 with diphenylsilane lead to the formation of insoluble dimeric bis(alkylzinc) N, N'-bis(2-pyridylmethyl) acetamidinate hydrides [zinc-bound methyl (5) or trimethylsilylmethyl group (6)]. These zinc hydrides decompose once dissolved under formation of elemental zinc thus hampering catalytic applications. Molecular structures of [(1)ZnCl2] as well as of the zinc complexes 2 to 6 are discussed. (c) 2011 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2011.01.033