[Cu(PCHO)2(2,2'-bipy)][BF4] | 876757-27-6

• 英文名称: [Cu(PCHO)2(2,2'-bipy)][BF4]
• 英文别名: [Cu(o-(diphenylphosphino)benzaldehyde)2(2,2'-bipyridine)][BF4]
• CAS: 876757-27-6
• 化学式: BF₄*C₄₈H₃₈CuN₂O₂P₂
• 分子量: 887.14
• InChiKey: JVHDQFDJVSPFSF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  2,2'-联吡啶 、 [Cu(o-(diphenylphosphino)benzaldehyde)2(acetonitrile)][BF4] 以 四氢呋喃 为溶剂， 以56%的产率得到[Cu(PCHO)2(2,2'-bipy)][BF4]
  参考文献：
  名称：

  Syntheses, characterization and crystal structures of [Cu(PCHO)2(2,2′-bipy)][BF4], [Cu2(PCHO)4(4,4′-bipy)][BF4]2 and [Cu2(PCHO)4(bptz)] [BF4]2 (PCHO=o-(diphenylphosphino)benzaldehyde and bptz=3,6-bis(2′-pyridyl)-1,2,4,5-tetrazine)

  摘要：

  Treatment of [Cu(PCHO)(2)(NCMe)][BF4] (1) (PCHO = o-(diphenylphosphino)benzaldehyde) with 2,2'-bipyridine produces the complex [Cu(PCHO)(2)(2,2'-bipy)][BF4](4), while the reactions of 1 with 4,4'-bipyridine and 3,6-bis(2'-pyridyl)-1,2,4,5-tetrazine (abbreviated as bptz) afford the dinuclear complexes [Cu-2(PCHO)(4)(4,4'-bipy)][BF4](2) (5) and [Cu-2(PCHO)(4)(bptz)][BF4](2) (6), respectively. The crystal structures of 4-6 have been determined by an X-ray diffraction study. The coordination about the Cu+ ion is trigonal for 5 and tetrahedral for 4 and 6, and there is no bonding between the aldehyde groups and the Cu+ ion in these compounds. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2005.08.008