[CoCl2(2,3,8,9-tetramethyl-1,4,7,10-tetraazacyclododeca-1,3,7,9-tetraene[N4])] | 646067-55-2

• 英文名称: [CoCl2(2,3,8,9-tetramethyl-1,4,7,10-tetraazacyclododeca-1,3,7,9-tetraene[N4])]
• 英文别名: [Co(DAED)Cl2]
• CAS: 646067-55-2
• 化学式: C₁₂H₂₀Cl₂CoN₄
• 分子量: 350.217
• InChiKey: OTUZVHXWAXQZEC-XYHOEUBASA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  乙二胺 、 2,3-丁二酮 、 cobalt(II) chloride 在 HCl 作用下， 以 乙醇 为溶剂， 以62%的产率得到[CoCl2(2,3,8,9-tetramethyl-1,4,7,10-tetraazacyclododeca-1,3,7,9-tetraene[N4])]
  参考文献：
  名称：

  Synthesis and Characterization of Cobalt(II) Complexes with Two Twelve‐Membered Tetraaza Macrocyclic Ligands

  摘要：

  Cobalt(H) complexes of the general composition CoLX2 {where X = Cl, 1/2 SO4, NO3, and SCN; L = 2,3,8,9-tetramethyl-1,4,7,10-tetraazacyclododeca-1,3,7,9-tetraene [N-4] (DAED) or 2,3,8,9-tetraphenyl-5,11-dimethyl-1,4,7,10-tetraazacyclododeca-1,3,7,9-tetraene[N-4] (BDAP)} have been prepared. On the basis of electronic and EPR spectral studies, the chloro, nitrato and thiocyanato complexes were found to have six-coordinate, octahedral geometry and the sulfato complexes were found to have five-coordinate, trigonal-bipyramidal geometry.

  DOI：

  10.1081/sim-120027318