[(η5-C6H6((t)Bu))Mn(CO)3] | 124184-15-2

• 英文名称: [(η5-C6H6((t)Bu))Mn(CO)3]
• CAS: 124184-15-2
• 化学式: C₁₃H₁₅MnO₃
• 分子量: 274.198
• InChiKey: UTVBTFHILPXERJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [(η5-C6H6((t)Bu))Mn(CO)3] 、 溶剂黄146 以 not given 为溶剂， 生成
  参考文献：
  名称：

  Photochemical Rearomatization and Dearomatization of Tricarbonyl(η⁵-cyclohexadienyl)manganese Complexes

  摘要：

  Photoirradiation of the tricarbonyl(eta(5)-cyclohexadienyl)manganese complexes 2 in dichloromethane or cyclohexane leads to the formation of the rearomatization products 3 in high yield, while photoirradiation of 2 in acetonitrile or dimethylformamide results in 3 and deaxomatization products 5 and 6 with the ratio 1(5 + 6) of ca. 1:1. In the presence of acetic acid the photochemical reaction of 2 both in dichloromethane and in acetonitrile exclusively yields 5 and 6. The photochemical reaction of 2 might be of significant utility in the synthesis of functionalized arenes and substituted cyclohexadienes.

  DOI：

  10.1021/om050953b
• 作为产物：
  描述：

  (η6-benzene)manganese tricarbonyl perchlorate 以 乙醚 、 二氯甲烷 为溶剂， 以60%的产率得到[(η5-C6H6((t)Bu))Mn(CO)3]
  参考文献：
  名称：

  Photochemical Rearomatization and Dearomatization of Tricarbonyl(η⁵-cyclohexadienyl)manganese Complexes

  摘要：

  Photoirradiation of the tricarbonyl(eta(5)-cyclohexadienyl)manganese complexes 2 in dichloromethane or cyclohexane leads to the formation of the rearomatization products 3 in high yield, while photoirradiation of 2 in acetonitrile or dimethylformamide results in 3 and deaxomatization products 5 and 6 with the ratio 1(5 + 6) of ca. 1:1. In the presence of acetic acid the photochemical reaction of 2 both in dichloromethane and in acetonitrile exclusively yields 5 and 6. The photochemical reaction of 2 might be of significant utility in the synthesis of functionalized arenes and substituted cyclohexadienes.

  DOI：

  10.1021/om050953b

文献信息

• Reduction and alkylation of (η6-arene)tricarbonylmanganese complexes using alkyl-substituted coenzyme NADH models
  作者：Lidong Cao、Li Zheng、Qiliang Huang

  DOI：10.1016/j.jorganchem.2014.06.021

  日期：2014.10

  direct tert-butyl group transfer was observed between t-BuBNAH and (η6-arene)Mn(CO)3+ complexes in reflux acetonitrile without a radical initiator, and the corresponding tert-butyl radical addition products were achieved. The substituents on the aromatic ring significantly influence the reactivity and chemoselectivity. The electron-withdrawing group helps to promote the reactions. The radical inhibition

  直接叔之间观察丁基基团转移被吨-BuBNAH和（η 6 -arene）的Mn（CO）3个+在回流的乙腈配合物没有自由基引发剂，和相应的叔丁基分别实现自由基的加成产物。芳环上的取代基显着影响反应性和化学选择性。吸电子基团有助于促进反应。自由基抑制实验表明，该反应可能是由单电子转移引发的自由基链过程。
• Indium-Mediated Alkyl Radical Addition to (η⁶-Arene)tricarbonylmanganese Complexes in Aqueous Media
  作者：Lidong Cao、Meihua Shen、Chaozhong Li

  DOI：10.1021/om050721c

  日期：2005.11.1

  Alkyl radical addition to (eta(6)-arene)tricarbonylmangenese complexes was investigated with SMI2, zinc, or indium as the radical initiator. Among them, the indium-mediated reactions of (eta(6)-arene)tricarbonylmangenese cations with various alkyl iodides in aqueous media afforded the corresponding radical addition-reduction products in moderate to excellent yields.