tricarbonyl[(2,3,4,5-η)-9,9-dichlorobicyclo[5.2.0]nona-2,4-dien-8-one]iron | 446859-60-5

• 英文名称: tricarbonyl[(2,3,4,5-η)-9,9-dichlorobicyclo[5.2.0]nona-2,4-dien-8-one]iron
• CAS: 446859-60-5
• 化学式: C₁₂H₈Cl₂FeO₄
• 分子量: 342.946
• InChiKey: VANLMEZEGRDVPD-FLUDSDCVSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  tricarbonyl[(2,3,4,5-η)-9,9-dichlorobicyclo[5.2.0]nona-2,4-dien-8-one]iron 、 乙酰氯 在 Et₃N 作用下， 以 四氢呋喃 为溶剂， 以95%的产率得到tricarbonyl[(2,3,4,5-η)-8-acetoxy-9,9-dichlorobicyclo[5.2.0]nona-2,4,7-triene]iron
  参考文献：
  名称：

  Reaction of (η4-cycloheptatriene)Fe(CO)3 with haloketenes: structure and reactivity of the cycloadducts

  摘要：

  Reaction of (eta(4)-cycloheptatriene)Fe(CO)(3) (1) with dichloroketene (2) generated by treatment of trichloroacetyl chloride with activated zinc. gave a [2 + 2] cycloadduct 3 along with a small amount of sigma,pi-allyl complex 4 and c-lactone-type 1:2 adduct 5. However. I reacted with 2 generated by treatment of dichloroacetylchloride with triethylamine to give a 1:2 ester adduct 13 as a main product, Complex 1 also reacted with chloroketene. which was generated by treatment of dichloroacetyl chloride with activated zinc, to give a [2 + 2] cycloadduct 23 in a better yield in comparison with the case of 2. The cycloadduct 3 was converted to several interesting compounds. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(01)01472-3
• 作为产物：
  描述：

  二氯乙酰氯 、 tricarbonyl((1,2,3,4-η)-1,3,5-cycloheptatriene)iron 在 Et₃N 作用下， 以 乙醚 为溶剂， 以46%的产率得到tricarbonyl[(2,3,4,5-η)-9,9-dichloro-8-dichloromethylcarbonyloxybicyclo[5.2.0]nona-2,4,7-triene]iron
  参考文献：
  名称：

  Reaction of (η4-cycloheptatriene)Fe(CO)3 with haloketenes: structure and reactivity of the cycloadducts

  摘要：

  Reaction of (eta(4)-cycloheptatriene)Fe(CO)(3) (1) with dichloroketene (2) generated by treatment of trichloroacetyl chloride with activated zinc. gave a [2 + 2] cycloadduct 3 along with a small amount of sigma,pi-allyl complex 4 and c-lactone-type 1:2 adduct 5. However. I reacted with 2 generated by treatment of dichloroacetylchloride with triethylamine to give a 1:2 ester adduct 13 as a main product, Complex 1 also reacted with chloroketene. which was generated by treatment of dichloroacetyl chloride with activated zinc, to give a [2 + 2] cycloadduct 23 in a better yield in comparison with the case of 2. The cycloadduct 3 was converted to several interesting compounds. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(01)01472-3