| 681457-41-0

• CAS: 681457-41-0
• 化学式: C₃₅H₃₄ClN₂PPt
• 分子量: 744.175
• InChiKey: KAGWHIONRQYMAH-SEPCIRIJSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  以 丙酮 、 甲苯 为溶剂， 生成
  参考文献：
  名称：

  Compound [PtPh₂(SMe₂)₂] as a Versatile Metalating Agent in the Preparation of New Types of [C,N,N‘] Cyclometalated Platinum Compounds

  摘要：

  The reactions of [PtPh2(SMe2)(2)] (1) with ligands RCH=NCH2CH2NMe2 (R = C6H5 (2a), 2-BrC6H4 (2b), 2,6-Cl2C6H3 (2c), 2-ClC6H4 (2d), and C6F5 (2e)) produced compounds [PtPh2{Me2NCH2CH2NCHR}] (3). Compounds 3 led to formation of three different types of [C,N,N'] platinum compounds, including platinum(II) compounds with a seven-membered metallacycle. The reactions of the cyclometalated compounds with triphenylphosphine were also studied.

  DOI：

  10.1021/om030674t