| 227960-36-3

• CAS: 227960-36-3
• 化学式: C₃₀H₂₆MoN₄O₄P₂
• 分子量: 664.448
• InChiKey: IKMRPWMEZHTDFN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  (bicyclo[2.2.1]hepta-2,5-diene)tetracarbonylmolybdenum(0) 、 1,5-di(2-pyridyl)-3,7-diphenyl-1,5,3,7-diazadiphosphacyclooctane 以 二氯甲烷 为溶剂， 以64%的产率得到
  参考文献：
  名称：

  Synthesis and structural studies of molybdenum and palladium complexes of 1,5-diaza-3,7-diphosphacyclooctane ligands

  摘要：

  1,5-Diaza-3;7-diphosphacyclooctanes form 1:1 complexes with the metal fragments Mo(CO)(4) and PdCl2. Two of these products along with a parent heterocycle have been structurally characterized. The [P(Ph)CH2N(2-pyridyl)CH2], ring is found in a crown conformation while its cis-Mo(CO)(4) complex adopts a chair-boat ligand conformation. On the other hand, the cis-PdCl2 complex of [P(Ph)CH2N(Bz)CH2](2) is found to retain a highly flattened crown ligand conformation Unlike rha related eight-membered heterocycle 1,3,5,7-tetraoxa-2,3,6,8-tetraphosphacyclooctane which behaves as a tetradentate ligand chelating homo- or hetero-bimetallics, coordination to a second metal by these complexes was not realized. (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(98)00413-6