K{trans-[PtCl₂{η¹-CH2C(O)CH3}(py)]} | 1581710-49-7

• 英文名称: K{trans-[PtCl₂{η¹-CH2C(O)CH3}(py)]}
• CAS: 1581710-49-7
• 化学式: C₈H₁₀Cl₂NOPt*K
• 分子量: 441.258
• InChiKey: OPKZOTIPPGZLOA-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  吡啶 、 K{trans-[PtCl₂{η¹-CH₂C(O)CH₃}(η²-C₂H₄)]} 以 丙酮 为溶剂， 反应 0.17h， 以110 mg的产率得到K{trans-[PtCl₂{η¹-CH2C(O)CH3}(py)]}
  参考文献：
  名称：

  New method for the synthesis of [PtCl{η1-CH2C(O)R}(N-N)] ketonyl derivatives starting from the Zeise’s salt

  摘要：

  In this work, the reactivity of the Zeise's salt, K[PtCl3(eta(2)-C2H4)], with ketones, in the presence of strong bases, has been studied. In these conditions the formation of metastable intermediate complexes of the type trans-[PtCl2{eta(1)-CH2C(O)R}(eta(2)-C2H4)], has been demonstrated by NMR spectroscopy. Further reaction with dinitrogen ligands (N-N) gives [PtCl{eta(1)-CH2C(O)R}(N-N)] complexes. This reactivity of the Zeise's anion can be exploited for the first general synthesis, in a one pot reaction, of r-carbon Pt(II) ketonyl derivatives with aliphatic or aromatic dinitrogen ligands (even if sterically hindered). (C) 2014 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2013.12.044