| 501371-32-0

• CAS: 501371-32-0
• 化学式: C₄₃H₆₂N₄OTi₂
• 分子量: 750.707
• InChiKey: DVWPAURWLNOHHG-UIDCWDIOSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 氢气 以 not given 为溶剂， 生成
  参考文献：
  名称：

  Chemistry Supported by Preorganized Binucleating Ligands:  Synthesis and Structural Characterization of Dititanium(III) μ-Methyl μ-Hydrido Species

  摘要：

  Binucleating bis(amidinate) ligands based on a 9,9-dimethylxanthene backbone have been used to prepare new dititanium(I-V) complexes of the general formula [bis(amidinate)]Ti2Cp2R4 (R = CH3, (CH3)-C-13, CD3). Reaction of these methyl derivatives with H-2 affords the dititanium(III) mu-methyl mu-hydrido derivatives [bis(amidinate)]Ti2Cp2(mu-R)(mu-H) (R = CH3, (CH3)-C-13, CD3), which have been characterized by single-crystal X-ray diffraction and NMR and IR spectroscopy. These complexes are rare examples of first-row-transition-metal alkyl hydrido species.

  DOI：

  10.1021/om020960p
• 作为产物：
  描述：

  、 iPr-L-Xan-H2 以 not given 为溶剂， 生成
  参考文献：
  名称：

  Chemistry Supported by Preorganized Binucleating Ligands:  Synthesis and Structural Characterization of Dititanium(III) μ-Methyl μ-Hydrido Species

  摘要：

  Binucleating bis(amidinate) ligands based on a 9,9-dimethylxanthene backbone have been used to prepare new dititanium(I-V) complexes of the general formula [bis(amidinate)]Ti2Cp2R4 (R = CH3, (CH3)-C-13, CD3). Reaction of these methyl derivatives with H-2 affords the dititanium(III) mu-methyl mu-hydrido derivatives [bis(amidinate)]Ti2Cp2(mu-R)(mu-H) (R = CH3, (CH3)-C-13, CD3), which have been characterized by single-crystal X-ray diffraction and NMR and IR spectroscopy. These complexes are rare examples of first-row-transition-metal alkyl hydrido species.

  DOI：

  10.1021/om020960p