(pentamethylcyclopentadienyl)2UCl(NS(phenyl)2) | 488789-04-4

• 英文名称: (pentamethylcyclopentadienyl)2UCl(NS(phenyl)2)
• CAS: 488789-04-4
• 化学式: C₃₂H₄₀ClNSU
• 分子量: 744.224
• InChiKey: CPVHBEXISOBEOV-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (pentamethylcyclopentadienyl)2UCl(NS(phenyl)2) 、 正戊烷 以 甲苯 为溶剂， 生成 (pentamethylcyclopentadienyl)2UCl(NS(phenyl)2)*0.5 pentane
  参考文献：
  名称：

  Uranium−Sulfilimine Chemistry:  Synthesis and Characterization of Cp*₂UCl(NSPh₂) and Cp*₂U(NSPh₂)₂

  摘要：

  Two imido derivatives of U(IV), CP*2UCl(NSPh2) (1; Cp* = pentamethylcyclopentadienyl) and CP*U-2(NSPh2)(2) (2), have been prepared in high yield from CP*2UCl2 and LiNSPh2. Alternatively, 1 and 2 can be synthesized by treating CP*2UCl[(CH2)(2)PPh2] with anhydrous HNSPh2. CP*U-2(NSPh2)(2) is the first structurally characterized uranium bis(sulfilimide) complex. Its short U-N distance suggests significant uranium-imido multiple-bond character.

  DOI：

  10.1021/om020678i
• 作为产物：
  描述：

  bis(pentamethylcyclopentadienyl)dichlorouranium(IV) 、 N-lithio-S,S-diphenylsulfilimine 以 甲苯 为溶剂， 以72%的产率得到(pentamethylcyclopentadienyl)2UCl(NS(phenyl)2)
  参考文献：
  名称：

  Uranium−Sulfilimine Chemistry:  Synthesis and Characterization of Cp*₂UCl(NSPh₂) and Cp*₂U(NSPh₂)₂

  摘要：

  Two imido derivatives of U(IV), CP*2UCl(NSPh2) (1; Cp* = pentamethylcyclopentadienyl) and CP*U-2(NSPh2)(2) (2), have been prepared in high yield from CP*2UCl2 and LiNSPh2. Alternatively, 1 and 2 can be synthesized by treating CP*2UCl[(CH2)(2)PPh2] with anhydrous HNSPh2. CP*U-2(NSPh2)(2) is the first structurally characterized uranium bis(sulfilimide) complex. Its short U-N distance suggests significant uranium-imido multiple-bond character.

  DOI：

  10.1021/om020678i