BPh2(1-N-7-azaindolyl-1,3-butanedionato) | 376390-38-4

• 英文名称: BPh2(1-N-7-azaindolyl-1,3-butanedionato)
• CAS: 376390-38-4
• 化学式: C₂₃H₁₉BN₂O₂
• 分子量: 366.227
• InChiKey: JLBYIQPMOGYAIK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  三苯基硼烷 、 1-N-7-azaindolyl-1,3-butanedione 以 四氢呋喃 为溶剂， 以83%的产率得到BPh2(1-N-7-azaindolyl-1,3-butanedionato)
  参考文献：
  名称：

  Syntheses and structures of new blue luminescent B(III) and Al(III) complexes: BPh2(acac-azain) and Al(CH3)(acac-azain)2, acac-azain=1-N-7-azaindolyl-1,3-butanedionato

  摘要：

  A novel blue luminescent ligand, 1-N-7-azaindolyl-1,3-butanedione (acac-azainH), has been synthesized and characterized structurally. The acac-azainH has a diketone structure in the solid state. The diketone form of acac-azainH is also dominant in solution. The acac-azainH molecule reacts readily with BPh3 and Al(CH3)(3) to form chelate complexes BPh2(acac-azain) (1) and Al(CH3)(acac-azain)(2) (2), respectively. The structure of 1 was determined by a single-crystal X-ray diffraction analysis. The acac-azainH molecule and compounds 1 and 2 are all blue luminescent but the luminescent efficiency is poor. In solution, compound 2 appears to exist in two isomeric forms. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(01)01017-8