[Pd(C(CH3)=N-2,6-Xyl)(dppe)(N(Ph)=CHPh)]BF4 | 1190269-45-4

• 英文名称: [Pd(C(CH3)=N-2,6-Xyl)(dppe)(N(Ph)=CHPh)]BF4
• CAS: 1190269-45-4
• 化学式: BF₄*C₄₉H₄₇N₂P₂Pd
• 分子量: 919.098
• InChiKey: LZQMUWPLSUPWGR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [Pd(Me)(dppe)(N(Ph)=C(H)Ph)]BF4 、 2,6-二甲基苯基异腈 以 四氢呋喃 为溶剂， 以0%的产率得到[Pd(C(CH3)=N-2,6-Xyl)(dppe)(N(Ph)=CHPh)]BF4
  参考文献：
  名称：

  Palladium Iminoacyl Imine Complexes: Strategies toward Imine Insertion

  摘要：

  The syntheses and characterization of a number of palladium complexes containing imine and/or iminoacyl groups are reported. Our strategies toward the insertion of imines into palladium iminoacyl complexes are outlined. The imine complexes [Pd(Me)(L-2){N(R')=C(H)Ph}]X (where L-2 = dppe, dppp, dppf, R' = Ph, Me, Bz; and X = BF4 or OTf) were prepared and fully characterized. [Pd(Me)(dppe){N(Ph)=C(H)Ph}]BF4 (1) and [Pd(Me)(dppp){N(Ph)=C(H)Ph}]OTf (4) were structurally characterized by X-ray crystallography. The iminoacyl-imine complexes [Pd{C(Me)=NXyl} (L-2){N=C(Me)OCH2CH2}]BF4 (L-2 = dppe, 12; dppp, 13) were prepared. The bis-imine complex [Pd(dppe){N=C(Me)OCH2CH2}][BF4](2) (14) resulting from disproportionation of 12 was also prepared and structurally characterized. Protonation of the iminoacyl fragment provided iminoacyl imine complex [Pd{C(CH3)=N(H)Xyl}(dppe){N(Bz)=CPhH}][BF4](2) (17), which was sufficiently stable to be structurally characterized, providing some insight into the coordination of these fragments of palladium.

  DOI：

  10.1021/om900574b