(m-C6H4(NHPPr(i)2)2)PdC2 | 916260-74-7

• 英文名称: (m-C6H4(NHPPr(i)2)2)PdC2
• CAS: 916260-74-7
• 化学式: C₁₈H₃₄Cl₂N₂P₂Pd
• 分子量: 517.755
• InChiKey: OFFFOXFAPXYYOP-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  (m-C6H4(NHPPr(i)2)2)PdC2 在 三乙胺 作用下， 以 氘代苯 为溶剂， 生成 (m-C6H3(NHPPr(i)2)2)PdCl*CH3CN
  参考文献：
  名称：

  Missing link: PCP pincer ligands containing P–N bonds and their Pd complexes

  摘要：

  New PCP ligands in which the phosphine donor arms are connected to the central aromatic ring via NH moieties and their (PCP)PdCl complexes have been prepared. One such (PCP)PdCl complex was characterized by X-ray diffractometry in the solid state. The (PCP)PdCl complexes are exceptionally robust towards oxygen and water despite the presence of P-N bonds. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2006.07.018
• 作为产物：
  描述：

  N,N'-bis(diisopropylphosphino)-1,3-benzenediamine 、 dichloro(cycloocta-1,5-diene)palladium (II) 以 氘代苯 为溶剂， 生成 (m-C6H4(NHPPr(i)2)2)PdC2
  参考文献：
  名称：

  Missing link: PCP pincer ligands containing P–N bonds and their Pd complexes

  摘要：

  New PCP ligands in which the phosphine donor arms are connected to the central aromatic ring via NH moieties and their (PCP)PdCl complexes have been prepared. One such (PCP)PdCl complex was characterized by X-ray diffractometry in the solid state. The (PCP)PdCl complexes are exceptionally robust towards oxygen and water despite the presence of P-N bonds. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2006.07.018