[Ru(η6-p-cymene)(1,1'-bis(diphenylphosphino)ferrocene))Cl]SnCl3 | 1389343-83-2

• 英文名称: [Ru(η6-p-cymene)(1,1'-bis(diphenylphosphino)ferrocene))Cl]SnCl3
• 英文别名: [Ru(η6-p-cymene)(dppf)Cl]SnCl3
• CAS: 1389343-83-2
• 化学式: C₄₄H₄₂ClFeP₂Ru*Cl₃Sn
• 分子量: 1050.2
• InChiKey: VGKQYBMZQKCRLU-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  tin(II) chloride dihdyrate 、 [(η(6)-p-cymene)RuCl(1,1'-bis(diphenylphosphino)ferrocene-P,P')]PF6 以 乙醇 、 苯 为溶剂， 以78%的产率得到[Ru(η6-p-cymene)(1,1'-bis(diphenylphosphino)ferrocene))Cl]SnCl3
  参考文献：
  名称：

  Synthesis and characterization of [Ru(η6-C10H14)(dppf)X][PF6] (X=Cl, Br, I, SnF3) compounds: The X-ray structure of [Ru(η6-C10H14)(dppf)Cl][SnCl3]·0.45CH2Cl2

  摘要：

  The arene-ruthenium complex [Ru(eta(6)-C10H14)(dppf)Cl]PF6 (1) was used as a precursor for the syntheses of the [Ru(eta(6)-C10H14)(dppf)Br]PF6 (2), [Ru(eta(6)-C10H14)(dppf)I]PF6 (3). [Ru(eta(6)-C10H14)(dppf)SnF3]PF6 (4) and [Ru(eta(6)-C10H14)(dppf)Cl][SnCl3]center dot 0.45CH(2)Cl(2) (5) complexes by its reactions with KBr, Kl, SnF2 and SnCl2. respectively. All of the compounds were characterized by NMR, IR, Fe-57 and Sn-119-Mossbauer spectroscopy, and cyclic voltammetry. The single-crystal X-ray structure analysis of the [Ru(eta(6)-C10H14)(dppf)Cl] [SnCl3]center dot 0.45CH(2)Cl(2) complex revealed the expected piano-stool geometry. Cyclic voltammograms of the complexes showed only one quasi-reversible electrochemical process, involving the oxidation of Fe(II) and Ru(II) at the same potential, which was confirmed by exhaustive electrolysis experiments. Fe-57-Mossbauer parameters obtained for the complexes (1-5) were fitted with one doublet corresponding to a site of one iron(II). The Sn-119-Mossbauer parameters of the complex (4) indicate that tin is tetra covalent. (c) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2012.05.002