Sodium dichloro-bis[N-butylsalicylideniminatoN,O]-ruthenate(III), | 1656994-68-1

• 英文名称: Sodium dichloro-bis[N-butylsalicylideniminatoN,O]-ruthenate(III),
• 英文别名: Na[RuCl₂(N-Bu-5-H-salim)₂]
• CAS: 1656994-68-1
• 化学式: C₂₂H₂₈Cl₂N₂O₂Ru*Na
• 分子量: 547.442
• InChiKey: PVNLCTATDKDQRN-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  水杨醛 以 乙醇 为溶剂， 生成 Sodium dichloro-bis[N-butylsalicylideniminatoN,O]-ruthenate(III),
  参考文献：
  名称：

  DNA Binding Properties of Two Ruthenium(III) Complexes Containing Schiff Bases Derived from Salicylaldehyde: Spectroscopic and Electrochemical Evidence of CT DNA Intercalation

  摘要：

  The interaction of CT DNA by two anionic Ru(III) complexes with N-substituted salicylidenimine ligands was investigated by spectroscopic titration and cyclic voltammetry. The result gives a surprising evidence for intercalation of DNA by the negatively charged complex species containing non typical intercalating ligands with K-b of order 10(4) M-1. Na[RuCl2(N-R-5-X-salim)(2)], where R represents butyl or phenyl and X = H, Cl, were characterized on the basis of elemental analysis, MALDI-TOF mass spectrometry, infrared, UV / visible spectroscopic measurements and cyclic voltammetry.

  DOI：

  10.5562/cca2216