oxo((triphenylphosphonio)imino)uranium(VI) tetraphenylphosphonium chloride | 182060-31-7

• 英文名称: oxo((triphenylphosphonio)imino)uranium(VI) tetraphenylphosphonium chloride
• CAS: 182060-31-7
• 化学式: C₁₈H₁₅Cl₄NOPU*C₂₄H₂₀P
• 分子量: 1011.53
• InChiKey: YHKDEFFKSZZNRF-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  tetraphenylphosphonium pentachloro-oxouranate(VI) 、 1,1,1-三甲基-N-(三苯基正膦亚基)硅烷胺 以 二氯甲烷 为溶剂， 以20%的产率得到oxo((triphenylphosphonio)imino)uranium(VI) tetraphenylphosphonium chloride
  参考文献：
  名称：

  Stable Analogs of the Uranyl Ion Containing the −NUN− Group

  摘要：

  A series of compounds containing the -N=U=N- group has been prepared. Their physical and chemical properties are reported. They adopt a trans configuration, and are thermally robust. The chemistry of some recently-prepared O=U=N- compounds is also described. These are the first examples of stable analogs of the uranyl ion UO22+. The factors that determine their stability are discussed.

  DOI：

  10.1021/ic951386v